Catalytic hydration of alkynes to ketones by a salen-gold(III) complex

被引：29
作者：
Chen, Tingting [1 ]
Cai, Chun [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Chem Engn Coll, Nanjing 210094, Jiangsu, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2015年 / 65卷
关键词：
Alkynes; Hydration; Ketones; Salen-gold(III) complex; HIGHLY EFFICIENT CATALYSTS; TERMINAL ALKYNES; BASE-COMPLEXES; GOLD CATALYSIS; HYDROAMINATION; AU(III);
D O I：
10.1016/j.catcom.2015.03.003
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A general atom-economical approach for the synthesis of ketones is demonstrated through hydration of a wide range of alkynes catalyzed by a salen-gold(III) complex in the presence of trifluoroacetic acid as the cocatalyst. Various terminal and internal alkynes were suitable substrates for the catalytic system. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：102 / 104
页数：3
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