Hexaphenylbenzene-based polymers of intrinsic microporosity

被引：70
|
作者：
Short, Rhys [1 ]
Carta, Mariolino [1 ]
Bezzu, C. Grazia [1 ]
Fritsch, Detlev [2 ]
Kariuki, Benson M. [1 ]
McKeown, Neil B. [1 ]
机构：
[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales
[2] Helmholtz Zentrum Geesthacht, Inst Mat Res, D-21502 Geesthacht, Germany
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 24期
基金：
英国工程与自然科学研究理事会;
关键词：
CRYSTALS; DERIVATIVES; ADSORPTION; MOLECULES; NETWORKS; CATIONS;
D O I：
10.1039/c1cc11717c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Microporous polymers derived from the 1,2- and 1,4-regioisomers of di(3',4'-dihydroxyphenyl)tetraphenylbenzene have very different properties with the former being composed predominantly of cyclic oligomers whereas the latter is of high molar mass suitable for the formation of robust solvent-cast films of high gas permeability.
引用
收藏
页码：6822 / 6824
页数：3
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