Hexaphenylbenzene-based polymers of intrinsic microporosity

被引：71

作者：

Short, Rhys ^{[1
]}

Carta, Mariolino ^{[1
]}

Bezzu, C. Grazia ^{[1
]}

Fritsch, Detlev ^{[2
]}

Kariuki, Benson M. ^{[1
]}

McKeown, Neil B. ^{[1
]}

机构：

[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales

[2] Helmholtz Zentrum Geesthacht, Inst Mat Res, D-21502 Geesthacht, Germany

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 24期

基金：

英国工程与自然科学研究理事会;

关键词：

CRYSTALS; DERIVATIVES; ADSORPTION; MOLECULES; NETWORKS; CATIONS;

D O I：

10.1039/c1cc11717c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Microporous polymers derived from the 1,2- and 1,4-regioisomers of di(3',4'-dihydroxyphenyl)tetraphenylbenzene have very different properties with the former being composed predominantly of cyclic oligomers whereas the latter is of high molar mass suitable for the formation of robust solvent-cast films of high gas permeability.

引用

页码：6822 / 6824

页数：3

共 31 条

[1] Highly permeable polymers for gas separation membranes [J].

Budd, Peter M. ;

McKeown, Neil B. .

POLYMER CHEMISTRY, 2010, 1 (01) :63-68

[2] Gas permeation parameters and other physicochemical properties of a polymer of intrinsic microporosity: Polybenzodioxane PIM-1 [J].

Budd, Peter M. ;

McKeown, Neil B. ;

Ghanem, Bader S. ;

Msayib, Kadhum J. ;

Fritsch, Detlev ;

Starannikova, Ludmila ;

Belov, Nikolai ;

Sanfirova, Olga ;

Yampolskii, Yuri ;

Shantarovich, Victor .

JOURNAL OF MEMBRANE SCIENCE, 2008, 325 (02) :851-860

[3] Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic nanoporous materials [J].

Budd, PM ;

Ghanem, BS ;

Makhseed, S ;

McKeown, NB ;

Msayib, KJ ;

Tattershall, CE .

CHEMICAL COMMUNICATIONS, 2004, (02) :230-231

[4] Solution-processed, organophilic membrane derived from a polymer of intrinsic microporosity [J].

Budd, PM ;

Elabas, ES ;

Ghanem, BS ;

Makhseed, S ;

McKeown, NB ;

Msayib, KJ ;

Tattershall, CE ;

Wang, D .

ADVANCED MATERIALS, 2004, 16 (05) :456-+

[5] A nanoporous network polymer derived from hexaazatrinaphthylene with potential as an adsorbent and catalyst support [J].

Budd, PM ;

Ghanem, B ;

Msayib, K ;

McKeown, NB ;

Tattershall, C .

JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (11) :2721-2726

[6] Novel spirobisindanes for use as precursors to polymers of intrinsic microporosity [J].

Carta, Mariolino ;

Msayib, Kadhurn J. ;

Budd, Peter M. ;

McKeown, Neil B. .

ORGANIC LETTERS, 2008, 10 (13) :2641-2643

[7] DIBENZO PARA DIOXIN [J].

CORDES, AW ;

FAIR, CK .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1974, B 30 (JUN15) :1621-1623

[8] Structural Features in Crystals of Derivatives of Benzene with Multiple Contiguous Phenyl Substituents [J].

Gagnon, Eric ;

Maris, Thierry ;

Arseneault, Pierre-Marc ;

Maly, Kenneth E. ;

Wuest, James D. .

CRYSTAL GROWTH & DESIGN, 2010, 10 (02) :648-657

[9] Tampering with Molecular Cohesion in Crystals of Hexaphenylbenzenes [J].

Gagnon, Eric ;

Halperin, Shira D. ;

Metivaud, Valerie ;

Maly, Kenneth E. ;

Wuest, James D. .

JOURNAL OF ORGANIC CHEMISTRY, 2010, 75 (02) :399-406

[10] Star-like substituted hexaarylbenzenes:: synthesis and mesomorphic properties [J].

Geng, YH ;

Fechtenkötter, A ;

Müllen, K .

JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (06) :1634-1641

← 1 2 3 4 →