Liquid-liquid extraction applied to metals separation from Waelz oxide

被引：8

作者：

Almela, A ^{[1
]}

Elizalde, MP ^{[1
]}

Danobeitia, I ^{[1
]}

机构：

[1] Univ Basque Country, Dept Quim Analit, E-48080 Bilbao, Spain

来源：

SEPARATION SCIENCE AND TECHNOLOGY | 1998年 / 33卷 / 15期

关键词：

D O I：

10.1080/01496399808545273

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal recovery from "Waelz oxide," the product obtained from steel foundry dusts through a pyrometallurgical process, and the slag obtained in this process has been carried out by liquid-liquid extraction. For this purpose, leaching of the solid samples was attained by microwave digestion with HCl. The extraction of 13 elements in the leachates was studied using the alkylthiophosphinic acid Cyanex 302 in kerosene and varying the acidity conditions and the extractant concentration. The experimental results on the extraction of cadmium, lead, and zinc have been compared with the theoretical behavior obtained by taking into account equilibrium extraction data reported for the extraction of these elements from synthetic individual solutions.

引用

页码：2411 / 2422

页数：12

共 11 条

[1] SOLVENT-EXTRACTION OF CADMIUM(II) FROM ACIDIC MEDIA BY CYANEX-302 [J].

ALMELA, A ;

ELIZALDE, MP .

HYDROMETALLURGY, 1995, 37 (01) :47-57

[2]

ALMELA A, 1997, THESIS U BASQUE COUN

[3]

[Anonymous], 1983, TRITAOOK3010 KTH DEP

[4] Extraction equilibria of Zn(II) from chloride medium by Cyanex 302 in toluene [J].

Benito, R ;

Menoyo, B ;

Elizalde, MP .

HYDROMETALLURGY, 1996, 40 (1-2) :51-63

[5]

Burguera M, 1996, QUIM ANAL, V15, P112

[6]

CUADRA A, 1992, QUIM IND, V38, P1

[7]

GOICOECHEA N, 1990, 1 C INT QUIM ANQUE T

[8]

LOPEZ FA, 1990, 1 C INT QUIM ANQUE T

[9] Extraction of lead(II) by Cyanex 302 in toluene, effect of Cyanex 301 on the extraction by Cyanex 302 [J].

Menoyo, B ;

Benito, R ;

Elizalde, MP .

SOLVENT EXTRACTION AND ION EXCHANGE, 1996, 14 (01) :69-88

[10]

NUNEZ A, 1990, 1 C INT QUIM ANQUE T

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