Atomic layer deposition of zirconium titanium oxide from titanium isopropoxide and zirconium chloride

被引:32
作者
Rahtu, A [1 ]
Ritala, M [1 ]
Leskelä, M [1 ]
机构
[1] Univ Helsinki, Dept Chem, FIN-00014 Helsinki, Finland
关键词
D O I
10.1021/cm0012062
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Atomic layer deposition of ZrxTiyOz thin films using titanium isopropoxide and zirconium chloride as precursors in a temperature range of 200-300 degreesC was studied. Instead of using water or other compounds as a separate oxygen source, titanium isopropoxide served as both an oxygen and a metal source. At 300 degreesC the growth rate was 1.2 Angstrom /cycle. The permittivity of the ZrxTiyOz films was 45-65, and the leakage current was 10(-4) A/cm(2) at 0.2 MV/cm. The films were studied by means of spectrophotometry, X-ray diffraction, energy-dispersive X-ray spectroscopy, ion beam analysis, and electrical measurements.
引用
收藏
页码:1528 / 1532
页数:5
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