Facile Reduction of a Uranyl(VI) β-ketoiminate Complex to U(IV) Upon Oxo Silylation

被引：56

作者：

Brown, Jessie L. ^{[1
]}

Mokhtarzadeh, Charles C. ^{[1
]}

Lever, Jeremie M. ^{[1
]}

Wu, Guang ^{[1
]}

Hayton, Trevor W. ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 11期

关键词：

EQUATORIAL COORDINATION; PENTAVALENT URANIUM; TERTIARY PHOSPHINE; CRYSTAL-STRUCTURES; SOLID-STATE; LIGANDS; ADDUCTS; CHEMISTRY; DICATION; BOND;

D O I：

10.1021/ic200387n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the uranyl beta-ketoiminate complex UO(2)((tBu)acnac)(2) (1) ((tBu)acnac = (t)BuNC(Ph)CHC(Ph)O) with Me(3)SiI, in the presence of Ph(3)P, results in the reductive silylation of the uranyl moiety and formation of the U(V) bis-silyloxide complex [Ph(3)PI][U(OSiMe(3))(2)I(4)] (2). Subsequent reaction of 2 with Lewis bases, such as 2,2'-bipyridine (bipy), 1,10-phenanthroline (phen), and tetrahydrofuran (THF), results in a further reduction of the metal center and isolation of the U(IV) complexes U(OSiMe(3))(2)I(2)(bipy)(2) (3), U(OSiMe(3))(2)I(2)-(phen)(2) (4), and [U(OSiMe(3))(2)I(THF)(4)][I(3)] (5), respectively.

引用

页码：5105 / 5112

页数：8

共 43 条

[1] URANYL COMPLEXES WITH (HEXAMETHYLDISILYL)AMIDO AND NONAFLUORO-TERT-BUTOXO LIGANDS
ANDERSEN, RA
[J]. INORGANIC CHEMISTRY, 1979, 18 (01) : 209 - 209
[2] [Anonymous], SHELXTL 6 12
[3] [Anonymous], 1999, SAINT SOFTW US GUID
[4] [Anonymous], SMART SOFTW US GUID
[5] Reduction and selective oxo group silylation of the uranyl dication
Arnold, Polly L.
Patel, Dipti
Wilson, Claire
Love, Jason B.
[J]. NATURE, 2008, 451 (7176) : 315 - U3
[6] Pentavalent uranyl complexes
Arnold, Polly L.
Love, Jason B.
Patel, Dipti
[J]. COORDINATION CHEMISTRY REVIEWS, 2009, 253 (15-16) : 1973 - 1978
[7] Uranium-mediated ring opening of tetrahydrofuran. Crystal structure of UI2(OCH2CH2CH2CH2I)(2)(Ph(3)P=O)(2)
Avens, LR
Barnhart, DM
Burns, CJ
McKee, SD
[J]. INORGANIC CHEMISTRY, 1996, 35 (02) : 537 - &
[8] STRUCTURAL CHEMISTRY OF DONOR-ACCEPTOR INTERACTIONS
BENT, HA
[J]. CHEMICAL REVIEWS, 1968, 68 (05) : 587 - &
[9] Oxygen and nitrogen Lewis base adducts of [UO2(OTf)2].: Crystal structures of polypyridine complexes with out-of-plane uranyl equatorial coordination
Berthet, JC
Nierlich, M
Ephritikhine, M
[J]. DALTON TRANSACTIONS, 2004, (17) : 2814 - 2821
[10] Controlled chemical reduction of uranyl salts into UX4(MeCN)4 (X = Cl, Br, I) with Me3SiX reagents
Berthet, Jean-Claude
Siffredi, Gerald
Thuery, Pierre
Ephritikhine, Michel
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, 25 (25) : 4017 - 4020

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