Electrical properties of La3+and Y3+ ions substituted Ni0.3Cu0.3 Zn0.4Fe2O4 nanospinel ferrites

被引:34
作者
Almessiere, M. A. [1 ,2 ]
Unal, B. [3 ,4 ]
Slimani, Y. [1 ]
Korkmaz, A. D. [5 ]
Baykal, A. [6 ]
Ercan, I [1 ]
机构
[1] Imam Abdulrahman Bin Faisal Univ, IRMC, Dept Biophys, POB 1982, Dammam 31441, Saudi Arabia
[2] Imam Abdulrahman Bin Faisal Univ, Coll Sci, Dept Phys, POB 1982, Dammam 31441, Saudi Arabia
[3] Istanbul Univ Cerrahpasa, Inst Forens Sci & Legal Med, Buyukcekmece Campus, TR-34500 Istanbul, Turkey
[4] Istanbul Univ Cerrahpasa, Inst Nanotechnol & Biotechnol, Buyukcekmece Campus, TR-34500 Istanbul, Turkey
[5] Istanbul Medeniyet Univ, Dept Chem, TR-34700 Istanbul, Uskudar, Turkey
[6] Imam Abdulrahman Bin Faisal Univ, Dept Nanomed Res, IRMC, POB 1982, Dammam 31441, Saudi Arabia
关键词
Spinel ferrites; Rare earth substitutions; Conductivity; Dielectric properties; ELECTROMAGNETIC PROPERTIES; DIELECTRIC-CONSTANT; MAGNETIC-PROPERTIES; NANOPARTICLES; CONDUCTIVITY; MICROWAVE; FILMS;
D O I
10.1016/j.rinp.2019.102755
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
La-Y substituted Ni-Cu-Zn nanospinel ferrites (NSFs) having the following formula Ni0.3Cu0.3Zn0.4LaxYxFe2-2xO4 (x = 0.0-0.10) were fabricated prepared by ultrasonic irradiation approach. The X-ray powder diffractometer (XRD), scanning electron microscope (SEM) and Fourier-transform infrared spectroscopy (FT-IR) were utilized to analyze the structure, vibration bands and morphology. The impedance spectroscopy technique was used for the analysis of electrical and dielectric properties of La3+ and Y3+ ions co-substituted Ni0.3Cu0.3Zn0.4Fe2O4 NSFs. Some important parameters such as ac conductivity, activation energy, dielectric constant and dielectric loss were examined as functions of frequencies and temperatures for a variety of La and Y co-substitution ratios. In general, ac conductivity is observed to fluctuate slightly with the elevated temperatures while its fluctuation level decreases somehow with an increase in co-substitution ratios. Furthermore, the frequency dependence of dielectric functions could be described by Koop's models based on Maxwell-Wagner theory, which elucidates the correlation between the polarizability coefficient and dielectric constant in inhomogeneous double-layer structures.
引用
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页数:10
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