Synthesis, Characterization and Electrical Properties of Both Pure and Cobalt-Doped Picromerite-Type Hydrated Double Salt K2Mg1-xCox(SO4)2•6H2O (x=0, 0.4)

被引:14
作者
Souemti, A. [1 ]
Lozano-Gorrin, A. D. [2 ]
Zayani, L. [1 ]
Essayes, S. Attia [1 ]
Abbassi, M. [1 ]
Lalla, E. [3 ]
Perez-Rodriguez, C. [2 ]
Chehimi, D. Ben Hassen [1 ]
机构
[1] Univ Carthage, Fac Sci Bizerte, Lab Applicat Chim Ressources & Subst Nat & Enviro, Zarzouna 7021, Bizerte, Tunisia
[2] Univ La Laguna, Dept Fis, Ave Astrofis Francisco Sanchez S-N, E-38206 Tenerife, Spain
[3] IFIN HH, Extreme Light Infrastruct Nucl Phys, POB MG-6, Bucharest 077125, Romania
关键词
Inorganic compounds; crystal growth; infrared spectroscopy; impedance spectroscopy; electrical properties; SULFATE HEXAHYDRATE; CRYSTAL; MG; CO; K3NA(SO4)(2); GROWTH; NI; CU;
D O I
10.1007/s11664-016-4622-2
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Polycrystalline samples of K2Mg1-xCox(SO4)(2)center dot 6H(2)O (x = 0, 0.4) have been prepared by the slow evaporation method at room temperature. X-ray diffraction experiments confirmed the formation of pure crystalline picromerite. The electrical properties of the anhydrous compound K2Mg1-xCox(SO4)(2) have been studied by means of complex impedance spectroscopy in the temperature range 340-420 degrees C. The alternating current conductivity measurements exhibit features of the universal power law. Electric modulus properties of both pure and cobalt-doped picromerite have been investigated within a wide range of temperature and frequency.
引用
收藏
页码:4418 / 4424
页数:7
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