Hyperspectral Modeling of Soil Organic Matter Based on Characteristic Wavelength in East China

Soil organic matter (SOM) is a key index of soil fertility. Visible and near-infrared (VNIR, 350-2500 nm) reflectance spectroscopy is an effective method for modeling SOM content. Characteristic wavelength screening and spectral transformation may improve the performance of SOM prediction. This study aimed to explore the optimal combination of characteristic wavelength selection and spectral transformation for hyperspectral modeling of SOM. A total of 219 topsoil (0-20 cm) samples were collected from two soil types in the East China. VNIR reflectance spectra were measured in the laboratory. Firstly, after spectral transformation (inverse-log reflectance (LR), continuum removal (CR) and first-order derivative reflectance (FDR)) of VNIR spectra, characteristic wavelengths were selected by competitive adaptive reweighted sampling (CARS) and uninformative variables elimination (UVE) algorithms. Secondly, the SOM prediction models were constructed based on the partial least squares regression (PLSR), random forest (RF) and support vector regression (SVR) methods using the full spectra and selected wavelengths, respectively. Finally, optimal SOM prediction models were selected for two soil types. The results were as follows: (1) The CARS algorithm screened 40-125 characteristic wavelengths from the full spectra. The UVE algorithm screened 105-884 characteristic wavelengths. (2) For two soil types and full spectra, CARS and UVE improved the SOM modeling precision based on the PLSR and SVR methods. The coefficient of determination (R-2) value in the validation of the CARS-PLSR (PLSR model combined with CARS) and CARS-SVR (SVR model combined CARS) models ranged from 0.69 to 0.95, and the relative percent deviation (RPD) value ranged from 1.74 to 4.31. Lin's concordance correlation coefficient (LCCC) values ranged from 0.83 to 0.97. The UVE-PLSR and UVE-SVR models showed moderate precision. (3) The PLSR and SVR modeling accuracies of Paddy soil were better than those for Shajiang black soil. RF models performed worse for both soil types, with the R-2 values of validation ranging from 0.22 to 0.68 and RPD values ranging from 1.01 to 1.60. (4) For Paddy soil, the optimal SOM prediction models (highest R-2 and RPD, lowest root mean square error (RMSE)) were CR-CARS-PLSR (R-2 and RMSE: 0.97 and 1.21 g/kg in calibration sets, 0.95 and 1.72 g/kg in validation sets, RPD: 4.31) and CR-CARS-SVR (R-2 and RMSE: 0.98 and 1.04 g/kg in calibration sets, 0.91 and 2.24 g/kg in validation sets, RPD: 3.37). For Shajiang black soil, the optimal SOM prediction models were LR-CARS-PLSR (R-2 and RMSE: 0.95 and 0.93 g/kg in calibration sets, 0.86 and 1.44 g/kg in validation sets, RPD: 2.62) and FDR-CARS-SVR (R-2 and RMSE: 0.99 and 0.45 g/kg in calibration sets, 0.83 and 1.58 g/kg in validation sets, RPD: 2.38). The results suggested that the CARS algorithm combined CR and FDR can significantly improve the modeling accuracy of SOM content.