The orientation of the principal axes of the electron dipolar interaction tensor in triplet state C60 monoadducts

被引：9
作者：
Ceola, S [1 ]
Corvaja, C [1 ]
Franco, L [1 ]
机构：
[1] Univ Padua, Dept Phys Chem, I-35131 Padua, Italy
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2003年 / 394卷
关键词：
fullerene derivatives; triplet state; EPR;
D O I：
10.1080/15421400390193657
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The time resolved EPR spectra of a fullerene monoadduct triplet state has been studied in nematic phase of E7. The EPR lineshape has been explained with a motionally averaged, preferentially oriented, triplet spectrum. From the knowledge of the order parameters of the C-60 adduct, obtained from the analysis of EPR spectra of a very similar C-60-nitroxide derivative dissolved in the same nematic solvent, it was possible to determine that the X principal axis of the triplet state dipolar tensor is parallel to the C-2 symmetry axis of the C-60 monoadduct.
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收藏
页码：31 / 43
页数：13
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