Lipases: Valuable catalysts for dynamic kinetic resolutions

被引：164

作者：

de Miranda, Amanda S. ^{[1
]}

Miranda, Leandro S. M. ^{[1
]}

de Souza, Rodrigo O. M. A. ^{[1
]}

机构：

[1] Univ Fed Rio de Janeiro, Inst Quim, Lab Biocatalysis & Organ Synth, BR-21941909 Rio De Janeiro, Brazil

来源：

BIOTECHNOLOGY ADVANCES | 2015年 / 33卷 / 05期

关键词：

Lipases; Dynamic kinetic resolution; Chemoenzymatic synthesis; Enantioselectivity; Racemization; Enzyme catalysis; CANDIDA-ANTARCTICA LIPASE; EFFICIENT ASYMMETRIC-SYNTHESIS; ALPHA-HYDROXYCARBOXYLIC ACIDS; BURKHOLDERIA-CEPACIA LIPASE; METHYL CARBOXYLIC-ACIDS; ALKALINE-EARTH SUPPORTS; METAL COMBO CATALYSIS; NANOZEOLITE-AT-ENZYME; ONE-POT SYNTHESIS; SECONDARY ALCOHOLS;

D O I：

10.1016/j.biotechadv.2015.02.015

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

Dynamic kinetic resolutions have proven to be a useful method for the preparation of enantiopure compounds from racemates, leading to the formation of a single enantiomer in theoretically 100% yield. Because lipases are ubiquitous, versatile, stereoselective and robust biocatalysts, they have been successfully applied as co-catalysts in these reactions, being mostly combined with metals in the chemoenzymatic dynamic kinetic resolutions of alcohols and amines. (C) 2015 Elsevier Inc. All rights reserved.

引用

页码：372 / 393

页数：22

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