Compositional dependence of properties of SnO-P2O5 glasses

被引：39
作者：
Cha, Jaemin [1 ]
Kubo, Tetsuro [1 ]
Takebe, Hiromichi [2 ]
Kuwabara, Makoto [3 ]
机构：
[1] Kyushu Univ, Grad Sch Engn Sci, Fukuoka 8168580, Japan
[2] Ehime Univ, Grad Sch Sci & Engn, Matsuyama, Ehime 7908577, Japan
[3] Kyushu Univ, Fac Engn Sci, Fukuoka 8168580, Japan
来源：
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN | 2008年 / 116卷 / 1356期
关键词：
tin phosphate glass; durability; Raman spectra; PO4 tetrahedral unit; polarizability;
D O I：
10.2109/jcersj2.116.915
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Binary SnO-P2O5 (SP) glasses with 52-72 SnO mol% were examined. Glass transition temperature, density, refractive index and absorption edge were studied for transparent SP glasses. The structure of SP glasses was evaluated by FT/IR and Raman spectroscopy. The water durability was investigated by weight loss and Raman spectroscopy for SP glass samples immersed in distilled water at 30-70 degrees C. Raman spectra indicated in the immersion test that Q(1) units form and Q(2) units decrease as a result of water attack upon the phosphate chains with increasing immersion time in 62SnO center dot 38P(2)O(5) glass and no structural change was observed in 72SnO center dot 28P(2)O(5) glass. The relationship between the properties and glass structure with chemical bonding is discussed. (C) 2008 The Ceramic Society of Japan. All rights reserved.
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收藏
页码：915 / 919
页数：5
相关论文
共 23 条
  • [1] Structure and properties of x SnO-(100-x)P2O5 glasses
    Bekaert, T
    Montagne, L
    Delevoye, L
    Palavit, G
    Revel, B
    [J]. COMPTES RENDUS CHIMIE, 2004, 7 (3-4) : 377 - 382
  • [2] THE SHORT-RANGE STRUCTURE OF ZINC POLYPHOSPHATE GLASS
    BROW, RK
    TALLANT, DR
    MYERS, ST
    PHIFER, CC
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1995, 191 (1-2) : 45 - 55
  • [3] PHOSPHATE-GLASS DISSOLUTION IN AQUEOUS-SOLUTIONS
    BUNKER, BC
    ARNOLD, GW
    WILDER, JA
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1984, 64 (03) : 291 - 316
  • [4] DEHYDRATION OF PHOSPHATE-GLASSES
    EBENDORFFHEIDEPRIEM, H
    SEEBER, W
    EHRT, D
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1993, 163 (01) : 74 - 80
  • [5] Effect of OH-content on thermal and chemical properties of SnO-P2O5 glasses
    Ehrt, Doris
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2008, 354 (2-9) : 546 - 552
  • [6] Hashimoto T., 2004, J CERAM SOC JPN S, V112, pS1193
  • [7] Hayashi A, 2004, J NON-CRYST SOLIDS, V345, P478, DOI [10.1016/j.jnoncrysol.2004.08.069, 10.1016/j.jnoncrysol.2004.069]
  • [8] Optical and thermal properties of binary calcium phosphate and barium phosphate glasses
    Lee, ETY
    Taylor, ERM
    [J]. OPTICAL MATERIALS, 2006, 28 (03) : 200 - 206
  • [9] Durable phosphate glasses with lower transition temperatures
    Marino, AE
    Arrasmith, SR
    Gregg, LL
    Jacobs, SD
    Chen, GR
    Duc, Y
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2001, 289 (1-3) : 37 - 41
  • [10] *MAT CHAR CTR, 1981, DOETIC11400 PAC NW L
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