Synthesis and crystal structure of a novel copper (II) complex with acetylenedicarboxylate and 2, 2′-bipyridine

被引：0

作者：

Li, MX ^{[1
]}

Shao, M

Dai, H

An, BL

Lu, WC

Zhu, Y

Du, CX

机构：

[1] Shanghai Univ, Dept Chem, Shanghai 200444, Peoples R China

[2] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2005年 / 16卷 / 10期

关键词：

copper complex; crystal structure; coordination polymer; acetylenedicarboxylate acid;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound [Cu (ADC) (2, 2'-bipy)](n) (ADC = C-2 (COO)(2)(2-)) was prepared and characterized by elemental analysis, IR spectroscopy, X-ray analysis, respectively. The analysis of the crystal structure reveals that the copper atom is five-coordinated with two nitrogen atoms of 2, 2'-bipy and three oxygen atoms of different acetylenedicarboxylate dianions. ADC as bridging ligands link the Cu (II) ions, forming coordination polymer structure.

引用

页码：1405 / 1408

页数：4

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