A homochiral Cu(I) coordination polymer based on achiral precursors and its photocatalytic properties

被引：26

作者：

He, Xiang ^{[1
]}

Fang, Kang ^{[1
]}

Guo, Xiao-Hai ^{[1
]}

Han, Jing ^{[2
]}

Lu, Xiao-Peng ^{[1
]}

Li, Ming-Xing ^{[1
]}

机构：

[1] Shanghai Univ, Innovat Drug Res Ctr, Dept Chem, Shanghai 200444, Peoples R China

[2] Xian Univ Technol, Dept Mat Phys & Chem, Xian 710048, Peoples R China

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 30期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORKS; SPONTANEOUS RESOLUTION; BUILDING-BLOCKS; CRYSTAL NETS; INDUCTION; CRYSTALLIZATION; RECOGNITION; SEPARATION; CATALYSIS; TOPOLOGY;

D O I：

10.1039/c5dt01328c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A homochiral three-dimensional framework material, [Cu-7(4-bpt)(6)(CN)(H2O)] (1) (4-bpt = 3,5-bis(4-pyridyl)-1,2,4-triazole), has been successfully synthesized by solvothermal reaction, which is generated through an unusual spontaneous asymmetrical crystallization from achiral precursors, and its photocatalytic properties in degradation of organic dyes are also investigated.

引用

页码：13545 / 13549

页数：5

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