Photoluminescence properties of monodispersed Mn2+ doped ZnS nanoparticles prepared in high temperature

被引:25
作者
Murugadoss, G. [1 ]
Rajamannan, B. [1 ]
Ramasamy, V. [1 ]
机构
[1] Annamalai Univ, Dept Phys, Annamalainagar 608002, Tamil Nadu, India
关键词
Semiconductor materials; TOPO; Photoluminescence; TEM; Particle size distribution; NANOCRYSTALS; SHAPE; CDS; LUMINESCENCE; SYMMETRY;
D O I
10.1016/j.molstruc.2011.02.026
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Photoluminescence properties of trioctylphosphine oxide (TOPO) capped ZnS:Mn2+ nanoparticles were investigated. The particles were synthesized using chemical precipitation method at 160 degrees C. The nanoparticles were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), particles size analyzer (PSA), Fourier transform infra-red spectrometer (FT-IR), ultraviolet-visible (UV-Vis) and photoluminescence (PL). The PL results showed that the yellow-orange emission peak centered at 580 nm. XRD and TEM analysis results reveal the formation of cubic structure ZnS:Mn2+ particles with an average size of 3.5 nm. The TOPO capped ZnS:Mn2+ nanoparticles showed enhanced luminescence property compared with that of the uncapped particles. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:202 / 206
页数:5
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