Palladium nanoparticles heterogeneous nucleation within organically grafted silica foams and their use as catalyst supports toward the Suzuki-Miyaura and Mizoroki-Heck coupling reactions

被引：44
作者：
Ungureanu, S. [1 ,2 ]
Deleuze, H. [2 ]
Babot, O. [2 ]
Achard, M-F [1 ]
Sanchez, C. [3 ]
Popa, M. I. [4 ]
Backov, R. [1 ]
机构：
[1] Univ Bordeaux 1, CNRS, UPR 8641, Ctr Rech Paul Pascal, F-33600 Pessac, France
[2] Univ Bordeaux 1, CNRS, ISM, F-33405 Talence, France
[3] Univ Paris 06, CNRS, UMR 7574, Lab Chim Mat Condensee Paris, F-75000 Paris, France
[4] Fac Chem Engn & Environm Protect, Iasi 700050, Romania
来源：
APPLIED CATALYSIS A-GENERAL | 2010年 / 390卷 / 1-2期
关键词：
Foams; Silica; Hybrid materials; Nanoparticles; Catalysis; INTEGRATIVE-CHEMISTRY; PD NANOPARTICLES; POROUS SILICA; EMULSION; GENERATION; PALLADACYCLES; ARYL; IMMOBILIZATION; ARYLATION; LIQUID;
D O I：
10.1016/j.apcata.2010.09.025
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Palladium nanoparticles supported within hybrid organic-inorganic foams have been generated The as-synthesized catalysts labeled Pd@gOrgano-Si(HIPE) (high internal phase emulsion) have been tested with or without addition of triphenylphosphine (PPh3) considering both the Suzuki-Miyaura and Mizoroki-Heck coupling reactions Particularly the catalysts Pd@gMercapto-Si(HIPE)-P4 and Pd@g3Amino-Si(HIPE)-P4 under addition of (PPh3) in a molar ratio 4 1 relative to palladium are offering good yields turnover and cycling performances for the Mizoroki-Heck coupling reaction (C) 2010 Elsevier B V All rights reserved
引用
收藏
页码：51 / 58
页数：8
相关论文
共 57 条
  • [51] First Pd@Organo-Si(HIPE) Open-Cell Hybrid Monoliths Generation Offering Cycling Heck Catalysis Reactions
    Ungureanu, Simona
    Deleuze, Herve
    Sanchez, Clement
    Popa, Marcel I.
    Backov, Renal
    [J]. CHEMISTRY OF MATERIALS, 2008, 20 (20) : 6494 - 6500
  • [52] One-pot syntheses of the first series of emulsion based hierarchical hybrid organic-inorganic open-cell monoliths possessing tunable functionality (Organo-Si(HIPE) series)
    Ungureanu, Simona
    Birot, Marc
    Laurent, Guillaume
    Deleuze, Herve
    Babot, Odile
    Julian-Lopez, Beatriz
    Achard, Marie-France
    Popa, Marcel Ionel
    Sanchez, Clement
    Backov, Renal
    [J]. CHEMISTRY OF MATERIALS, 2007, 19 (23) : 5786 - 5796
  • [53] Syntheses and characterization of new organically grafted silica foams
    Ungureanu, Simona
    Laurent, Guillaume
    Deleuze, Herve
    Babot, Odile
    Achard, Marie F.
    Popa, Marcel I.
    Sanchez, Clement
    Backov, Renal
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2010, 360 (1-3) : 85 - 93
  • [54] Microstructures of porous silica prepared in aqueous and nonaqueous emulsion templates
    Yi, GR
    Yang, SM
    [J]. CHEMISTRY OF MATERIALS, 1999, 11 (09) : 2322 - +
  • [55] Synthesis of hierarchically porous silica and metal oxide beads using emulsion-templated polymer scaffolds
    Zhang, H
    Hardy, GC
    Khimyak, YZ
    Rosseinsky, MJ
    Cooper, AI
    [J]. CHEMISTRY OF MATERIALS, 2004, 16 (22) : 4245 - 4256
  • [56] Synthesis of hierarchically porous inorganic-metal site-isolated nanocomposites
    Zhang, Haifei
    Hussain, Irshad
    Brust, Mathias
    Cooper, Andrew I.
    [J]. CHEMICAL COMMUNICATIONS, 2006, (24) : 2539 - 2541
  • [57] Synthesis and applications of emulsion-templated porous materials
    Zhang, HF
    Cooper, AI
    [J]. SOFT MATTER, 2005, 1 (02) : 107 - 113
123456