Microstructural evolution of YSZ electrolyte aerosol-deposited on porous NiO-YSZ

被引:36
作者
Choi, Jong-Jin [1 ]
Choi, Joon-Hwan [1 ]
Ryu, Jungho [1 ]
Hahn, Byung-Dong [1 ]
Kim, Jong-Woo [1 ]
Ahn, Cheol-Woo [1 ]
Yoon, Woon-Ha [1 ]
Park, Dong-Soo [1 ]
机构
[1] Korea Inst Mat Sci, Funct Ceram Grp, Chang Won 642831, Gyeongnam, South Korea
关键词
Microstructure-final; Grain size; ZrO2; Fuel cells; Aerosol deposition; OXIDE FUEL-CELLS; ZIRCONIA FILMS; FABRICATION; SOFC; TEMPERATURE; MECHANISM;
D O I
10.1016/j.jeurceramsoc.2012.04.024
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Dense, crack-free, similar to 7.5 mu m thick, 8 mol% yttria stabilized zirconia (YSZ) film was aerosol deposited on porous NiO-YSZ anode substrates at room temperature without additional high-temperature sintering. The films' microstructures and gas permeability were observed after annealing at various temperatures. The dense, gas-tight film that was observed up to 1000 degrees C became porous at higher temperatures probably due to structural instability related to oxygen non-stoichiometry. A cell using such film as electrolyte showed an open cell voltage of 1.10 V and a maximum power density of 0.51 W/cm(2) at 750 degrees C. (c) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3249 / 3254
页数:6
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