Phosphonites based on the paracyclophane backbone: New ligands for highly rhodium-catalyzed hydrogenation

被引：53

作者：

Zanotti-Gerosa, A ^{[1
]}

Malan, C ^{[1
]}

Herzberg, D ^{[1
]}

机构：

[1] Chirotech Technol Ltd, Cambridge CB4 0WG, England

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 23期

关键词：

D O I：

10.1021/ol0166193

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The synthesis of new phosphonites with a chiral paracyclophane backbone is described. The rhodium complexes derived from the phosphonites bearing biphenoxy and binaphthoxy substituents are highly active and highly selective catalysts for the asymmetric hydrogenation of dehydroamino acids and esters.

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页码：3687 / 3690

页数：4

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