Synthesis of Olefin-Oxazoline Ligands (OlefOx) by Rhodium(III)-Catalyzed Oxidative Olefination

被引：39

作者：

Schroeder, Nils ^{[1
]}

Besset, Tatiana ^{[2
]}

Glorius, Frank ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

[2] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1098 XH Amsterdam, Netherlands

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 04期

关键词：

C?H activation; olefination; olefins; oxazolines; rhodium; CHIRAL DIENE LIGANDS; C-H BONDS; ENANTIOSELECTIVE CATALYSIS; ASYMMETRIC CATALYSIS; STEERING LIGANDS; DIRECT ARYLATION; BORONIC ACIDS; EFFICIENT; FUNCTIONALIZATION; ACTIVATION;

D O I：

10.1002/adsc.201100711

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The rhodium(III)-catalyzed oxidative olefination of 2-aryloxazolines is described and has been employed for the synthesis of olefin-oxazoline ligands (OlefOx). The highly modular synthesis starting from readily available 2-aryloxazolines can be performed under an atmosphere of air as the terminal oxidant with catalytic amounts of copper(II)-acetate.

引用

页码：579 / 583

页数：5

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