Bulky formamidinate complexes of lithium:: the first examples of η2:η1-C=N,N′ metal amidinate coordination

被引：21

作者：

Cole, ML

Davies, AJ

Jones, C

Junk, PC ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[2] Cardiff Univ, Sch Chem, Ctr Fundamental & Appl Main Grp Chem, Cardiff CF10 3AT, Wales

来源：

NEW JOURNAL OF CHEMISTRY | 2005年 / 29卷 / 11期

关键词：

D O I：

10.1039/b511519a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The lithium complexes [Li{N(Ar) C(H) N(Ar)}(pmdeta)], where Ar = 2,6- R2C6H3 (R = Me ( 1), Et ( 2) and Pr-i ( 3)) and pmdeta = N, N, N', N '', N ''-pentamethyldiethylenetriamine, have been synthesised and their solid state structures determined by X-ray methods. Compounds 1 - 3 comprise a Li( pmdeta) centre coordinated by a bulky formamidinate in either the E-syn or E-anti isomeric form. The structures of compound 3 and one unique molecular unit of compound 1 ( E-anti isomer) display coordination of the pendant amidinate imine, and can therefore be considered the first examples of eta(2):eta(1)- C=N, N' metal amidinate coordination.

引用

页码：1404 / 1408

页数：5

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