Anomalous decays in Nd3+ doped LaAlO3 single crystal

被引:10
作者
Bednarkiewicz, A. [1 ]
Deren, P. J. [1 ]
Lemanski, K. [1 ]
机构
[1] Polish Acad Sci, Inst Low Temp & Struct Res, PL-50422 Wroclaw, Poland
关键词
Neodymium; Luminescence decays; Judd-Ofelt theory; Optical properties; Perovskites; SPECTROSCOPIC CHARACTERIZATION; OPTICAL-PROPERTIES; TM3+ IONS; LAGAO3; EMISSION; LUMINESCENCE; TEMPERATURE; DEPENDENCE; SPECTRA; NDGAO3;
D O I
10.1016/j.jpcs.2015.05.005
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Luminescence decays of metastable Nd3+:F-4(3/2) level were measured and studied in wide of 10-300 K temperature range and compared with the radiative lifetimes derived from standard Judd-Ofelt theory. Nearly resonant cross-relaxation was found to non-radiatively depopulate the metastable level already in 10 K, whereas above 50 K increased reabsorption of radiation and thermalization of higher Stark component of the F-4(3/2) level occur, which resulted in the Boltzmann population of this metastable Nd3+ level and anomalous increase of luminescence decays with temperature increment. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:102 / 105
页数:4
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