(Acetone-κO){6,6′-di-tert-butyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]-diphenolato-κ4O,N,N′,O′}zinc(II)

被引：1

作者：

Eltayeb, Naser Eltaher ^{[2
]}

Teoh, Siang Guan ^{[2
]}

Chantrapromma, Suchada ^{[3
]}

Fun, Hoong-Kun ^{[1
]}

Adnan, Rohana ^{[2
]}

机构：

[1] Univ Sains Malaysia, Sch Phys, X Ray Crystallog Unit, George Town 11800, Malaysia

[2] Univ Sains Malaysia, Sch Chem Sci, George Town 11800, Malaysia

[3] Prince Songkla Univ, Fac Sci, Dept Chem, Hat Yai 90112, Songkhla, Thailand

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536808011215

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The molecule of the title compound, [Zn(C28H30N2O2)-(CH3COCH3)], lies across a mirror plane with the Zn-II ion and the acetone molecule on the mirror plane. The Zn-II ion is in a five-coordinate distorted square-pyramidal N2O3 environment, with the two imine N and two phenolic O atoms of the tetradentate Schiff base dianion in the basal plane and the acetone molecule in the apical position. The central benzene ring makes a dihedral angle of 16.5 (2) degrees with the two outer phenolate rings. In the crystal structure, the molecules are arranged into antiparallel columns along the a axis.

引用

页码：M738 / U1067

页数：12

共 12 条

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