A convenient method for the aromatic amino-Claisen rearrangement of N(1,1-disubstituted-allyl)anilines

被引：0

作者：

Cooper, MA ^{[1
]}

Lucas, MA ^{[1
]}

Taylor, JM ^{[1
]}

Ward, AD ^{[1
]}

Williamson, NM ^{[1
]}

机构：

[1] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia

来源：

SYNTHESIS-STUTTGART | 2001年 / 04期

关键词：

amino-Claisen; rearrangement; aromatic amines; alkenes; alkynes;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-(1, 1-Disubstituted-allyl)anilines are rearranged cleanly and in high yield to 2-(3,3-disubstituted-allyl)anilines using a catalytic amount of p-toluenesulfonic acid in acetonitrile/water (10:1).

引用

页码：621 / 625

页数：5

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