Mid-infrared fiber-optics reflectance spectroscopy: A noninvasive technique for remote analysis of painted layers. Part II: Statistical analysis of spectra

被引:19
作者
Fabbri, M [1 ]
Picollo, M [1 ]
Porcinai, S [1 ]
Bacci, M [1 ]
机构
[1] CNR, IROE Nello Carrara, I-50127 Florence, Italy
关键词
fiber-optics FT-IR spectroscopy; reflectance spectroscopy; noninvasive analysis; painted layers; PCA; Mahalanobis distance;
D O I
10.1366/0003702011952181
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Mid-infrared fiber-optics reflectance spectroscopy supported by classification procedures based on the Mahalanobis distance in the principal component space was applied to investigate laboratory samples simulating actual paintings. The spectral data obtained :cere analyzed by means of principal component analysis (PCA:). The application of PCA to first-derivative spectra resulted as a robust method of processing spectral data and made it possible to distinguish the binding medium and/or the pigment/dye. and to classify test samples by means of the Mahalanobis distance discrimination method.
引用
收藏
页码:428 / 433
页数:6
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