Electron swarm parameters of the hydrofluoroolefine HFO1234ze

被引:62
作者
Chachereau, A. [1 ]
Rabie, M. [1 ]
Franck, C. M. [1 ]
机构
[1] ETH, Power Syst & High Voltage Labs, Phys Str 3, CH-8092 Zurich, Switzerland
关键词
HFO1234ze; C3H2F4; swarm parameter; electron attachment; 1,3,3,3-tetrafluoro-1-propene; three-body attachment; ATTACHMENT;
D O I
10.1088/0963-0252/25/4/045005
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
In this contribution, the electron swarm parameters of the hydrofluoroolefine HFO1234ze (systematic name trans-1,3,3,3-tetrafluoro-1-propene) are experimentally investigated. The analysis of the electron avalanche current measured in a pulsed Townsend experiment yields the effective ionization rate coefficient, the electron drift velocity and the longitudinal electron diffusion coefficient. The subsequent ion current is analyzed as well, to obtain separately the ionization and attachment rate coefficients. Measurements in pure HFO1234ze at different pressures show that the effective ionization rate is strongly influenced by three-body attachment and the three-body attachment rate coefficient is derived.
引用
收藏
页数:12
相关论文
共 23 条
[1]   THE 3-BODY ELECTRON-ATTACHMENT TO A MOLECULE [J].
ALEKSANDROV, NL .
USPEKHI FIZICHESKIKH NAUK, 1988, 154 (02) :177-206
[2]  
Aschwanden T., 1985, THESIS
[3]   DER STROMVERLAUF EINER ELEKTRONENLAWINE MIT DIFFUSION [J].
BRAMBRING, J .
ZEITSCHRIFT FUR PHYSIK, 1964, 179 (05) :532-&
[4]  
Christophorou L G, 1984, ELECT DENSE GASES SW
[5]   Obtaining precise electron swarm parameters from a pulsed Townsend setup [J].
Dahl, Dominik A. ;
Teich, Timm H. ;
Franck, Christian M. .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2012, 45 (48)
[6]  
Hogue C, 2011, CHEM ENG NEWS, V89, P31
[7]  
Hunter S. R., 1982, Gaseous Dielectrics III. Proceedings of the Third International Symposium on Gaseous Dielectrics, P7
[8]   ELECTRON-ATTACHMENT TO THE PERFLUOROALKANES N-CNF2N+2(N=1-6) USING HIGH-PRESSURE SWARM TECHNIQUES [J].
HUNTER, SR ;
CHRISTOPHOROU, LG .
JOURNAL OF CHEMICAL PHYSICS, 1984, 80 (12) :6150-6164
[9]   ANOMALOUS ELECTRON-ATTACHMENT PROPERTIES OF PERFLUOROPROPYLENE (1-C3F6) AND THEIR EFFECT ON THE BREAKDOWN STRENGTH OF THIS GAS [J].
HUNTER, SR ;
CHRISTOPHOROU, LG ;
MCCORKLE, DL ;
SAUERS, I ;
ELLIS, HW ;
JAMES, DR .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1983, 16 (04) :573-580
[10]   ELECTRON-ATTACHMENT AND IONIZATION PROCESSES IN CF4, C2F6, C3F8, AND N-C4F10 [J].
HUNTER, SR ;
CARTER, JG ;
CHRISTOPHOROU, LG .
JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (02) :693-703