Self-assembly of chiral luminescent lanthanide coordination bundles

被引:164
作者
Leonard, Joseph P.
Jensen, Paul
McCabe, Thomas
O'Brien, John E.
Peacock, Robert D.
Kruger, Paul E.
Gunnlaugsson, Thorfinnur [1 ]
机构
[1] Trinity Coll Dublin, Sch Chem, Ctr Synth & Chem Biol, Dublin 2, Ireland
[2] Univ Canterbury, Coll Sci, Dept Chem, Christchurch 8020, New Zealand
[3] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland
关键词
D O I
10.1021/ja073049e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis and characterization of several highly ordered lanthanide complexes formed by the use of f-metal directed supramolecular synthesis is described. These unique self-assemblies or bundles are chiral as well as luminescent, where the lanthanide-based emission is observed upon excitation of the ligands (antennae) employed. These structures also give rise to chiral lanthanide luminescence (using CPL) demonstrating the chiral nature of these self-assemblies.
引用
收藏
页码:10986 / +
页数:3
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