Kaolin Bleaching by Leaching Using Phosphoric Acid Solutions

被引:0
作者
Hernandez Hernandez, Roman A. [1 ]
Legorreta Garcia, Felipe [1 ]
Hernandez Cruz, Leticia E. [1 ]
Bedolla Jacuinde, Arnoldo [2 ]
机构
[1] Univ Autonoma Estado Hidalgo, Area Acad Ciencias Tierra & Mat, Carretera Pachuca Tulancingo,Km 4-5 S-N, Mineral De La Reforma 42184, Hgo, Mexico
[2] Univ Michoacana, Inst Invest Met, Morelia 58000, Michoacan, Mexico
关键词
Leaching; Phosphoric acid; Kaolin; Iron; ORGANIC-ACIDS; OXALIC-ACID; IRON-OXIDES; DISSOLUTION; PHOSPHATE;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This paper presents a study of kaolin ore bleaching from the municipality of Agua Blanca of Iturbide, Hidalgo, Mexico. This process was carried out using solutions of phosphoric acid as the leaching reagent for the iron dissolution process. It is well known that iron oxide is the major contaminant of clay minerals and silicate used in industry. These contents should be decreased, usually by 0.1%, to achieve a required whiteness index of 90% (ISO) or higher. The whitening improves its economic value, making it possible to use it as a high-quality raw material in industries such as ceramics and paper. For this purpose, we examined the effect of parameters such as the concentration of the leaching reagent (0.10 M, 0.50 M, 1 M, and 3 M), temperature (298-373 K), and pH level (1, 2 and 3). The experimental results showed that the studied variables have a great influence over the ability to obtain an iron dissolution percentage of more than 98% after 2 hours and 373 K.
引用
收藏
页码:198 / 202
页数:5
相关论文
共 20 条
  • [1] Interaction of phosphate with iron(III) in acidic medium, equilibrium and kinetic studies
    Al-Sogair, F
    Marafie, HM
    Shuaib, NM
    Ben Youngo, H
    El-Ezaby, MS
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2002, 55 (09) : 1097 - 1109
  • [2] Effect of organic acids on ferric iron removal from iron-stained kaolinite
    Ambikadevi, VR
    Lalithambika, M
    [J]. APPLIED CLAY SCIENCE, 2000, 16 (3-4) : 133 - 145
  • [3] Arun S., 2003, J AM CERAM SOC, V86, P1850
  • [4] Avgustinik A.I., 1983, CERAMICA
  • [5] Flocculation and dewatering of kaolin suspensions in the presence of polyacrylamide and surfactants
    Besra, L
    Sengupta, DK
    Roy, S
    Ay, P
    [J]. INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 2002, 66 (1-4) : 203 - 232
  • [6] SELECTIVE EXTRACTION OF AMORPHOUS IRON-OXIDES BY EDTA FROM A DANISH SANDY LOAM
    BORGGAARD, OK
    [J]. JOURNAL OF SOIL SCIENCE, 1979, 30 (04): : 727 - 734
  • [7] Bleaching of Brazilian kaolins using organic acids and fermented medium
    deMesquita, LMS
    Rodrigues, T
    Gomes, SS
    [J]. MINERALS ENGINEERING, 1996, 9 (09) : 965 - 971
  • [8] Biobeneficiation of mineral raw materials
    Groudev, SN
    [J]. MINERALS & METALLURGICAL PROCESSING, 1999, 16 (04) : 19 - 28
  • [9] Hosseini M. R., 2015, APPL CLAY SCI
  • [10] Dissolution of iron oxide using oxalic acid
    Lee, Sung Oh
    Tran, Tam
    Jung, Byoung Hi
    Kim, Seong Jun
    Kim, Myong Jun
    [J]. HYDROMETALLURGY, 2007, 87 (3-4) : 91 - 99