Structure and mechanical performance of nitrogen doped diamond-like carbon films

被引:0
作者
Zhang, Huayu [1 ]
Liu, Liangxue
Wang, Yulei
Ma, Hongtao
Liu, Fanxin
机构
[1] Shenzhen Grad Sch, Harbin Inst Technol, Shenzhen 518055, Peoples R China
[2] SAE Technol Dev Dongguan Co Ltd, Dongguan 523087, Peoples R China
关键词
nitrogen doped diamond-like carbon films; ECR-CVD; structure; mechanical performance; TETRAHEDRAL AMORPHOUS-CARBON; THIN-FILMS; ELECTRICAL-PROPERTIES; ION-IMPLANTATION; VACUUM-ARC; DEPOSITION; DLC; TEMPERATURE; TECHNOLOGY; RESISTANCE;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nitrogen doped diamond-like carbon (DLC:N) films were prepared by electron cyclotron resonance chemical vapor deposition (ECR-CVD) on polycrystalline Si chips. Film thickness is about 50 rim. Auger electron spectroscopy (AES) was used to evaluate nitrogen content, and increasing N-2 flow improved N content from 0 to 7.6%. Raman and X-ray photoelectron spectroscopy (XPS) analysis results reveal N-sp(3)C and N-sp(2)C structure. With increasing the N2 flow, sp(3)C decreases from 73.74% down to 42.66%, and so does N-sp(3)C from 68.04% down to 20.23%. The hardness decreases from 29.18 GPa down to 19.74 GPa, and the Young's modulus from 193.03 GPa down to 144.52 GPa.
引用
收藏
页码:491 / 494
页数:4
相关论文
共 24 条
[1]   Surface properties of ultra-thin tetrahedral amorphous carbon films for magnetic storage technology [J].
Casiraghi, C ;
Ferrari, AC ;
Ohr, R ;
Chu, D ;
Robertson, J .
DIAMOND AND RELATED MATERIALS, 2004, 13 (4-8) :1416-1421
[2]   Blood compatibility and sp3/sp2 contents of diamond-like carbon (DLC) synthesized by plasma immersion ion implantation-deposition [J].
Chen, JY ;
Wang, LP ;
Fu, KY ;
Huang, N ;
Leng, Y ;
Leng, YX ;
Yang, P ;
Wang, J ;
Wan, GJ ;
Sun, H ;
Tian, XB ;
Chu, PK .
SURFACE & COATINGS TECHNOLOGY, 2002, 156 (1-3) :289-294
[3]   Contact resistance measurement of bonded copper interconnects for three-dimensional integration technology [J].
Chen, KN ;
Fan, A ;
Tan, CS ;
Reif, R .
IEEE ELECTRON DEVICE LETTERS, 2004, 25 (01) :10-12
[4]   Influence of nitrogen ion energy on the Raman spectroscopy of carbon nitride films [J].
Cheng, YH ;
Tay, BK ;
Lau, SP ;
Shi, X ;
Qiao, XL ;
Sun, ZH ;
Chen, JG ;
Wu, YP ;
Xie, CS .
DIAMOND AND RELATED MATERIALS, 2001, 10 (12) :2137-2144
[5]   The use of non-contact AFM with nanoindentation techniques for measuring mechanical properties of carbon nitride thin films [J].
Chowdhury, S ;
Laugier, MT .
APPLIED SURFACE SCIENCE, 2004, 233 (1-4) :219-226
[6]   Characterization of amorphous and nanocrystalline carbon films [J].
Chu, PK ;
Li, LH .
MATERIALS CHEMISTRY AND PHYSICS, 2006, 96 (2-3) :253-277
[7]   Characterisation of nitrogen modified diamond-like carbon films deposited by radio-frequency plasma enhanced chemical vapour deposition [J].
Dorner-Reisel, A ;
Kübler, L ;
Irmer, G ;
Reisel, G ;
Schöps, S ;
Klemm, V ;
Müller, E .
DIAMOND AND RELATED MATERIALS, 2005, 14 (3-7) :1073-1077
[8]   Low-temperature investigation of paramagnetic centres in tetrahedral amorphous carbon deposited by S-bend FCVA [J].
Fanchini, G ;
Tagliaferro, A ;
Dasgupta, D ;
Laurenti, E ;
Ferrari, AC ;
Teo, KBK ;
Milne, WI ;
Robertson, J .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2002, 299 :840-845
[9]   XPS and laser Raman analysis of hydrogenated amorphous carbon films [J].
Filik, J ;
May, PW ;
Pearce, SRJ ;
Wild, RK ;
Hallam, KR .
DIAMOND AND RELATED MATERIALS, 2003, 12 (3-7) :974-978
[10]   A new method for evaluating the scratch resistance of diamond-like carbon films by the nano-scratch technique [J].
Huang, LY ;
Zhao, JW ;
Xu, KW ;
Lu, J .
DIAMOND AND RELATED MATERIALS, 2002, 11 (07) :1454-1459