Iodofluorination of alkenes and alkynes promoted by iodine and 4-iodotoluene difluoride

被引：37

作者：

Conte, P ^{[1
]}

Panunzi, B ^{[1
]}

Tingoli, M ^{[1
]}

机构：

[1] Univ Naples Federico II, Fac Agr, I-80055 Portici, NA, Italy

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 03期

关键词：

hypervalent iodine; electrophilic iodination; fluoroiodoalkanes; fluoroiodoalkenes;

D O I：

10.1016/j.tetlet.2005.11.029

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It was found that a mixture of molecular iodine and 4-iodotoluene difluoride are useful to generate in situ the couple 'IF' that was able to add in a Markovnikov fashion and with prevalent anti-stereoselectivity to various alkenes and alkynes. (c) 2005 Elsevier Ltd. All rights reserved.

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页码：273 / 276

页数：4

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