Facile electrosynthesis of Fe (Ni/Co) hydroxyphosphate as a bifunctional electrocatalyst for efficient water splitting

被引：27
作者：
Bahar, P. T. [1 ]
Lokhande, A. C. [1 ]
Jo, Eunae [1 ]
Pawar, B. S. [2 ]
Gang, M. G. [1 ]
Pawar, S. M. [2 ]
Kim, J. H. [1 ]
机构：
[1] Chonnam Natl Univ, Dept Mat Sci & Engn, Optoelect Convergence Res Ctr, Gwangju 500757, South Korea
[2] Dongguk Univ, Div Phys & Semicond Sci, Seoul 100715, South Korea
来源：
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2019年 / 70卷
基金：
新加坡国家研究基金会;
关键词：
Bifunctional electrocatalyst; Electrodeposition; Hydroxyphosphate; TOF; REACTION OER ELECTROCATALYST; METAL-ORGANIC FRAMEWORK; OXYGEN EVOLUTION; ENERGY-CONVERSION; NICKEL FOAM; FILMS; IRON; HYDROXIDE; CATALYSTS; COBALT;
D O I：
10.1016/j.jiec.2018.09.041
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Porous iron-nickel hydroxyphosphate and iron-cobalt hydroxyphosphate electrodes are prepared by one-step electrodeposition method. The as-prepared iron-nickel hydroxyphosphate and iron-cobalt hydroxyphosphate electrodes show excellent performance for water splitting with high catalytic activity towards the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), with a lower overpotential of 220 and 235 mV for the OER and 145 and 160 mV for the HER, respectively. Moreover, two-electrode electrolyzer using iron-nickel hydroxyphosphate as both the anode and cathode requires a cell voltage of 1.65 V while iron-cobalt hydroxyphosphate requires cell voltage of 1.67 V to gain current density of 10 mA cm(-2). (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：116 / 123
页数：8
相关论文
共 45 条
[1]   Recent Trends and Perspectives in Electrochemical Water Splitting with an Emphasis on Sulfide, Selenide, and Phosphide Catalysts of Fe, Co, and Ni: A Review [J].
Anantharaj, Sengeni ;
Ede, Sivasankara Rao ;
Sakthikumar, Kuppan ;
Karthick, Kannimuthu ;
Mishra, Soumyaranjan ;
Kundu, Subrata .
ACS CATALYSIS, 2016, 6 (12) :8069-8097
[2]  
[Anonymous], 2014, ANGEW CHEM-GER EDIT
[3]   SILAR deposited iron phosphate as a bifunctional electrocatalyst for efficient water splitting [J].
Babar, P. T. ;
Lokhande, A. C. ;
Shim, H. J. ;
Gang, M. G. ;
Pawar, B. S. ;
Pawar, S. M. ;
Kim, Jin Hyeok .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2019, 534 :350-356
[4]   Thermally oxidized porous NiO as an efficient oxygen evolution reaction (OER) electrocatalyst for electrochemical water splitting application [J].
Babar, P. T. ;
Lokhande, A. C. ;
Gang, M. G. ;
Pawar, B. S. ;
Pawar, S. M. ;
Kim, Jin Hyeok .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2018, 60 :493-497
[5]   Electrocatalytic performance evaluation of cobalt hydroxide and cobalt oxide thin films for oxygen evolution reaction [J].
Babar, P. T. ;
Lokhande, A. C. ;
Pawar, B. S. ;
Gang, M. G. ;
Jo, Eunjin ;
Go, Changsik ;
Suryawanshi, M. P. ;
Pawar, S. M. ;
Kim, Jin Hyeok .
APPLIED SURFACE SCIENCE, 2018, 427 :253-259
[6]   Annealing temperature dependent catalytic water oxidation activity of iron oxyhydroxide thin films [J].
Babar, P. T. ;
Pawar, B. S. ;
Lokhande, A. C. ;
Gang, M. G. ;
Jang, J. S. ;
Suryawanshi, M. P. ;
Pawar, S. M. ;
Kim, Jin Hyeok .
JOURNAL OF ENERGY CHEMISTRY, 2017, 26 (04) :757-761
[7]   Cobalt Iron Hydroxide as a Precious Metal-Free Bifunctional Electrocatalyst for Efficient Overall Water Splitting [J].
Babar, Pravin ;
Lokhande, Abhishek ;
Shin, Hyeong Ho ;
Pawar, Bharati ;
Gang, Myeng Gil ;
Pawar, Sambhaji ;
Kim, Jin Hyeok .
SMALL, 2018, 14 (07)
[8]   Cost-Effective Alkaline Water Electrolysis Based on Nitrogen- and Phosphorus-Doped Self-Supportive Electrocatalysts [J].
Balogun, Muhammad-Sadeeq ;
Qiu, Weitao ;
Huang, Yongchao ;
Yang, Hao ;
Xu, Ruimei ;
Zhao, Wenxia ;
Li, Gao-Ren ;
Ji, Hongbing ;
Tong, Yexiang .
ADVANCED MATERIALS, 2017, 29 (34)
[9]   Nanostructured materials on 3D nickel foam as electrocatalysts for water splitting [J].
Chaudhari, Nitin K. ;
Jin, Haneul ;
Kim, Byeongyoon ;
Lee, Kwangyeol .
NANOSCALE, 2017, 9 (34) :12231-12247
[10]   Nonstoichiometric Oxides as Low-Cost and Highly-Efficient Oxygen Reduction/Evolution Catalysts for Low-Temperature Electrochemical Devices [J].
Chen, Dengjie ;
Chen, Chi ;
Baiyee, Zarah Medina ;
Shao, Zongping ;
Ciucci, Francesco .
CHEMICAL REVIEWS, 2015, 115 (18) :9869-9921
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