Tunable copper-catalyzed chemoselective hydrogenolysis of biomass-derived γ-valerolactone into 1,4-pentanediol or 2-methyltetrahydrofuran

被引：185
作者：
Du, Xian-Long [1 ]
Bi, Qing-Yuan [1 ]
Liu, Yong-Mei [1 ]
Cao, Yong [1 ]
He, He-Yong [1 ]
Fan, Kang-Nian [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
来源：
GREEN CHEMISTRY | 2012年 / 14卷 / 04期
基金：
中国国家自然科学基金;
关键词：
SELECTIVE HYDROGENOLYSIS; PROPYLENE-GLYCOL; DIMETHYL MALEATE; CONVERSION; HYDROGENATION; GLYCEROL; TETRAHYDROFURAN; TRANSFORMATION; CELLOBIOSE; BIOFUELS;
D O I：
10.1039/c2gc16599f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Direct conversion of gamma-valerolactone, which is one of the most significant cellulose-derived compounds, into 1,4-pentanediol was carried out by chemoselective hydrogenolysis catalyzed by a simple yet versatile copper-zirconia catalyst. Depending on the reaction conditions, 2-methyltetrahydrofuran could also be obtained in excellent yields.
引用
收藏
页码：935 / 939
页数：5
相关论文
共 40 条
[1]   Selective heterogeneously catalyzed hydrogenations [J].
Augustine, RL .
CATALYSIS TODAY, 1997, 37 (04) :419-440
[2]  
Ayoub P. M., 2008, [No title captured], Patent No. [WO 2008/142 127, 5697987]
[3]   γ-Valerolactone Ring-Opening and Decarboxylation over SiO2/Al2O3 in the Presence of Water [J].
Bond, Jesse Q. ;
Alonso, David Martin ;
West, Ryan M. ;
Dumesic, James A. .
LANGMUIR, 2010, 26 (21) :16291-16298
[4]   Integrated Catalytic Conversion of γ-Valerolactone to Liquid Alkenes for Transportation Fuels [J].
Bond, Jesse Q. ;
Alonso, David Martin ;
Wang, Dong ;
West, Ryan M. ;
Dumesic, James A. .
SCIENCE, 2010, 327 (5969) :1110-1114
[5]   Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "Top 10" revisited [J].
Bozell, Joseph J. ;
Petersen, Gene R. .
GREEN CHEMISTRY, 2010, 12 (04) :539-554
[6]   Catalytic routes for the conversion of biomass into liquid hydrocarbon transportation fuels [J].
Carlos Serrano-Ruiz, Juan ;
Dumesic, James A. .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (01) :83-99
[7]   Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals [J].
Chheda, Juben N. ;
Huber, George W. ;
Dumesic, James A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) :7164-7183
[8]   The roll of chemocatalysis in the establishment of the technology platform "Renewable resources" [J].
Claus, Peter ;
Vogel, Herbert .
CHEMICAL ENGINEERING & TECHNOLOGY, 2008, 31 (05) :678-699
[9]   Chemical routes for the transformation of biomass into chemicals [J].
Corma, Avelino ;
Iborra, Sara ;
Velty, Alexandra .
CHEMICAL REVIEWS, 2007, 107 (06) :2411-2502
[10]   Conversion of cellobiose into sorbitol in neutral water medium over carbon nanotube-supported ruthenium catalysts [J].
Deng, Weiping ;
Liu, Mi ;
Tan, Xuesong ;
Zhang, Qinghong ;
Wang, Ye .
JOURNAL OF CATALYSIS, 2010, 271 (01) :22-32
1234