Judd-Ofelt analysis of Ho3+ doped in ceramic CaSc2O4

被引:18
作者
Georgescu, Serban [1 ]
Stefan, Angela [1 ,2 ]
Toma, Octavian [1 ]
Voiculescu, Ana-Maria [1 ]
机构
[1] Natl Inst Laser Plasma & Radiat Phys, Magurele Ilfov 077125, Romania
[2] Univ Bucharest, Fac Phys, Magurele Ilfov 077125, Romania
关键词
CaSc2O4; Judd-Ofelt; Ho3+; RARE-EARTH IONS; OPTICAL-ABSORPTION INTENSITIES; ENERGY-TRANSFER; UP-CONVERSION; SPECTROSCOPIC PROPERTIES; FLUORIDE GLASSES; CALCIUM SCANDATE; SINGLE-CRYSTALS; LUMINESCENCE; PROBABILITIES;
D O I
10.1016/j.jlumin.2015.02.040
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
A Judd-Ofelt analysis was performed on a calcium scandate (CaSc2O4) ceramic sample doped with 2 at% Ho3+. Using the measured lifetime of I-5(7) level to calibrate the absorption spectrum, the Judd-Ofelt parameters were obtained: Omega(2) = 3.78 x 10(-20) cm(2), Omega(4) = 5.17 x 10(-20) cm(2), and Omega(6) = 1.92 x 10(-20) cm(2). The electric-dipole and magnetic-dipole transition probabilities, radiative lifetimes and luminescence branching ratios were calculated. The quantum efficiency of the green emitting levels (F-5(4), S-5(2)) was found: 54%. The calibration method also allowed the estimation of the 'effective' thickness of the ceramic sample: approximately eight times greater than the geometric thickness. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:174 / 179
页数:6
相关论文
共 38 条
[1]  
Barnes N.P., 2004, HDB LASER TECHNOLOGY, VII, P383
[2]   ELECTRONIC ENERGY LEVELS IN TRIVALENT LANTHANIDE AQUO IONS .I. PR3+ ND3+ PM3+ SM3+ DY3+ HO3+ ER3+ AND TM3+ [J].
CARNALL, WT ;
FIELDS, PR ;
RAJNAK, K .
JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (10) :4424-&
[3]   SPECTRAL INTENSITIES OF TRIVALENT LANTHANIDES AND ACTINIDES IN SOLUTION .2. PM3+ SM3+ EU3+ GD3+ TB3+ DY3+ AND HO3+ [J].
CARNALL, WT ;
FIELDS, PR ;
RAJNAK, K .
JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (10) :4412-&
[4]   Optical spectroscopy of Ho3+ and Tm3+ in Ca3Sc2Ge3O12 crystals [J].
Cavalli, E ;
Belletti, A ;
Bigotta, S ;
Toncelli, A ;
Tonelli, M .
JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 365 (1-2) :1-7
[5]   Energy levels and optical spectroscopy of Er3+ in Gd2O3 nanocrystals [J].
Chen, Xueyuan ;
Ma, En ;
Liu, Guokui .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (28) :10404-10411
[6]   Cross relaxation in CaTiO3 and LaAlO3 perovskite nanocrystals doped with Ho3+ ions [J].
Deren, P. J. ;
Lemanski, K. .
JOURNAL OF LUMINESCENCE, 2014, 154 :62-67
[7]   Magnetic dipole and electric quadrupole transitions in the trivalent lanthanide series: Calculated emission rates and oscillator strengths [J].
Dodson, Christopher M. ;
Zia, Rashid .
PHYSICAL REVIEW B, 2012, 86 (12)
[8]   Modeling upconversion of erbium doped microcrystals based on experimentally determined Einstein coefficients [J].
Fischer, Stefan ;
Steinkemper, Heiko ;
Loeper, Philipp ;
Hermle, Martin ;
Goldschmidt, Jan Christioph .
JOURNAL OF APPLIED PHYSICS, 2012, 111 (01)
[9]   RELATION BETWEEN ABSORPTION AND EMISSION PROBABILITIES IN LUMINESCENT CENTERS IN IONIC SOLIDS [J].
FOWLER, WB ;
DEXTER, DL .
PHYSICAL REVIEW, 1962, 128 (05) :2154-&
[10]   Spectroscopic properties of Yb-doped scandium based compounds Yb:CaSC2O4,Yb:SrSc2O4 and Yb:SC2SiO5 [J].
Gaume, R ;
Viana, B ;
Derouet, J ;
Vivien, D .
OPTICAL MATERIALS, 2003, 22 (02) :107-115