Novel Bronsted-Lewis acidic di-cationic ionic liquid for efficient conversion carbohydrate to platform compound

被引：17
作者：
Guo, Weihao [1 ,2 ]
Zuo, Minghui [1 ,2 ]
Zhao, Jian [1 ,2 ]
Li, Chao [1 ,2 ]
Xu, Qiaoliang [1 ,2 ]
Xu, Chunzhao [1 ,2 ]
Wu, Hongfeng [1 ,2 ]
Sun, Zhizhong [1 ,2 ]
Chu, Wenyi [1 ,2 ]
机构：
[1] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
[2] Coll Heilongjiang Prov, Key Lab Chem Engn Proc & Technol High Efficiency, Harbin 150080, Peoples R China
来源：
CELLULOSE | 2020年 / 27卷 / 12期
基金：
黑龙江省自然科学基金;
关键词：
Bronsted-Lewis acidic di-cationic ionic liquids; Glucose; 5-Hydroxymethylfurfural (5-HMF); 5-Ethoxymethylfurfural (5-EMF); Density functional theory calculations (DFT); GLUCOSE CONVERSION; BIOMASS; DEHYDRATION; FRUCTOSE; CHEMICALS; CATALYST; TRANSFORMATION; SUCROSE; FUELS; HMF;
D O I：
10.1007/s10570-020-03275-7
中图分类号：
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号：
0805 ; 080502 ; 0822 ;
摘要：
A series of Bronsted-Lewis acidic di-cationic ionic liquids (BLAILs) were synthesized and the catalytic properties of glucose conversion to 5-hydroxymethylfurfural (5-HMF) were investigated. The experimental results showed that the ionic liquid with aluminum trichloride as Lewis acid anion (BLAIL-5) exhibited good catalytic performance. Under the best reaction conditions, the yield of the glucose conversion into 5-HMF and 5-EMF were 71% and 66%, respectively. In addition, the yield of cellulose to 5-HMF is 41%. The optimized catalytic system could be reused for 5 times without significant catalytic performance loss. In addition, the mechanism of BLAIL-5 promoting glucose conversion to 5-HMF was studied by density functional theory calculation (DFT).
引用
收藏
页码：6897 / 6908
页数：12
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