Novel Bronsted-Lewis acidic di-cationic ionic liquid for efficient conversion carbohydrate to platform compound

被引：17

作者：

Guo, Weihao ^{[1
,2
]}

Zuo, Minghui ^{[1
,2
]}

Zhao, Jian ^{[1
,2
]}

Li, Chao ^{[1
,2
]}

Xu, Qiaoliang ^{[1
,2
]}

Xu, Chunzhao ^{[1
,2
]}

Wu, Hongfeng ^{[1
,2
]}

Sun, Zhizhong ^{[1
,2
]}

Chu, Wenyi ^{[1
,2
]}

机构：

[1] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China

[2] Coll Heilongjiang Prov, Key Lab Chem Engn Proc & Technol High Efficiency, Harbin 150080, Peoples R China

来源：

CELLULOSE | 2020年 / 27卷 / 12期

基金：

黑龙江省自然科学基金;

关键词：

Bronsted-Lewis acidic di-cationic ionic liquids; Glucose; 5-Hydroxymethylfurfural (5-HMF); 5-Ethoxymethylfurfural (5-EMF); Density functional theory calculations (DFT); GLUCOSE CONVERSION; BIOMASS; DEHYDRATION; FRUCTOSE; CHEMICALS; CATALYST; TRANSFORMATION; SUCROSE; FUELS; HMF;

D O I：

10.1007/s10570-020-03275-7

中图分类号：

TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];

学科分类号：

0805 ; 080502 ; 0822 ;

摘要：

A series of Bronsted-Lewis acidic di-cationic ionic liquids (BLAILs) were synthesized and the catalytic properties of glucose conversion to 5-hydroxymethylfurfural (5-HMF) were investigated. The experimental results showed that the ionic liquid with aluminum trichloride as Lewis acid anion (BLAIL-5) exhibited good catalytic performance. Under the best reaction conditions, the yield of the glucose conversion into 5-HMF and 5-EMF were 71% and 66%, respectively. In addition, the yield of cellulose to 5-HMF is 41%. The optimized catalytic system could be reused for 5 times without significant catalytic performance loss. In addition, the mechanism of BLAIL-5 promoting glucose conversion to 5-HMF was studied by density functional theory calculation (DFT).

引用

页码：6897 / 6908

页数：12

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