Preparation of a Poly-nanocage Dynamer: Correlating the Growth of Polymer Strands Using Constitutional Dynamic Chemistry and Heteroleptic Aggregation

被引：46

作者：

Fan, Jian ^{[1
]}

Saha, Manik Lal ^{[1
]}

Song, Bo

Schoenherr, Holger

Schmittel, Michael ^{[1
]}

机构：

[1] Univ Siegen, Ctr Micro & Nanochem & Engn Organ Chem I, D-57068 Siegen, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 01期

关键词：

ORTHOGONAL BINDING INTERACTIONS; PI-PI STACKING; SUPRAMOLECULAR POLYMERS; METALLOSUPRAMOLECULAR POLYMERS; COVALENT CHEMISTRY; METAL COORDINATION; MOLECULAR CAGES; MAIN-CHAIN; TRANSFORMATION; COMBINATION;

D O I：

10.1021/ja209879h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A metallosupramolecular prismatic nanocage with altogether six reactive aldehyde terminals was utilized as a sophisticated "monomer" in a template-directed constitutional dynamic imine polymerization to prepare an unprecedented triple-stranded dynamer. To analyze the correlated growth in its three congener strands, a fully covalent triple-armed star polymer was fabricated from the metallodynamer through capping, imine reduction, and removal of the template. Atomic force microscopy analysis of 68 triple-armed star polymer molecules suggests that the growth of their arms is correlated to similar to 72%.

引用

页码：150 / 153

页数：4

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