Nanocrystalline cellulose grafted phthalocyanine: a heterogeneous catalyst for selective aerobic oxidation of alcohols and alkyl arenes at room temperature in a green solvent

被引:37
作者
Chauhan, Prashant [1 ]
Yan, Ning [1 ,2 ]
机构
[1] Univ Toronto, Fac Forestry, Toronto, ON M5S 3B3, Canada
[2] Univ Toronto, Dept Chem Engn & Appl Chem, Toronto, ON M5S 3E5, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
EFFICIENT; GRAPHENE;
D O I
10.1039/c4ra16869k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Copper-tetrasulfonate phthalocyanine was incorporated on cellulose nanocrystals to act as a high yield, heterogeneous, and selective catalyst for the aerobic oxidation of alcohols and alkyl arenes to the corresponding carbonyl groups in an aqueous green solvent.
引用
收藏
页码:37517 / 37520
页数:4
相关论文
共 29 条
[11]   Selective Oxidation of Benzyl Alcohol Over Copper Phthalocyanine Immobilized on MCM-41 [J].
Hamza, A. ;
Srinivas, D. .
CATALYSIS LETTERS, 2009, 128 (3-4) :434-442
[12]   Cationic surface functionalization of cellulose nanocrystals [J].
Hasani, Merima ;
Cranston, Emily D. ;
Westman, Gunnar ;
Gray, Derek G. .
SOFT MATTER, 2008, 4 (11) :2238-2244
[13]  
Kadish K. M., 2010, PORPHYRIN SCI APPL C, V14-16
[14]   Nanocelluloses: A New Family of Nature-Based Materials [J].
Klemm, Dieter ;
Kramer, Friederike ;
Moritz, Sebastian ;
Lindstrom, Tom ;
Ankerfors, Mikael ;
Gray, Derek ;
Dorris, Annie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (24) :5438-5466
[15]  
Larock R. C., 2018, Comprehensive Organic Transformation
[16]   TEMPO-Oxidized Nanocellulose Participating as Crosslinking Aid for Alginate-Based Sponges [J].
Lin, Ning ;
Bruzzese, Cecile ;
Dufresne, Alain .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (09) :4948-4959
[17]   Aqueous aerobic oxidation of alkyl arenes and alcohols catalyzed by copper(II) phthalocyanine supported on three-dimensional nitrogen-doped graphene at room temperature [J].
Mahyari, Mojtaba ;
Laeini, Mohammad Sadegh ;
Shaabani, Ahmad .
CHEMICAL COMMUNICATIONS, 2014, 50 (58) :7855-7857
[18]  
Parshall G.W., 1992, HOMOGENEOUS CATALYSI
[19]   Influence of drying method on the material properties of nanocellulose I: thermostability and crystallinity [J].
Peng, Yucheng ;
Gardner, Douglas J. ;
Han, Yousoo ;
Kiziltas, Alper ;
Cai, Zhiyong ;
Tshabalala, Mandla A. .
CELLULOSE, 2013, 20 (05) :2379-2392
[20]   Efficient and highly selective aqueous oxidation of alcohols and sulfides catalyzed by reusable hydrophobic copper (II) phthalocyanine [J].
Rezaeifard, Abdolreza ;
Jafarpour, Maasoumeh ;
Naeimi, Atena ;
Salimi, Mehri .
INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 15 :230-234