Heavy metal removal from water/wastewater by nanosized metal oxides: A review

被引:1726
作者
Hua, Ming [1 ]
Zhang, Shujuan [1 ]
Pan, Bingcai [1 ]
Zhang, Weiming [1 ]
Lv, Lu [1 ]
Zhang, Quanxing [1 ]
机构
[1] Nanjing Univ, State Key Lab Pollut Control & Resource Reuse, Sch Environm, Nanjing 210046, Jiangsu, Peoples R China
关键词
Nanosized metal oxides; Heavy metals; Removal; Water treatment; Hybrid adsorbent; Nanocomposite; ABSORPTION SPECTROMETRIC DETERMINATION; ADSORPTION-DESORPTION REVERSIBILITY; FE3O4 MAGNETIC NANOPARTICLES; HYDROUS MANGANESE-DIOXIDE; SURFACTANT-COATED ALUMINA; WASTE-WATER; AQUEOUS-SOLUTIONS; IRON-OXIDE; EFFICIENT REMOVAL; HUMIC-ACID;
D O I
10.1016/j.jhazmat.2011.10.016
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Nanosized metal oxides (NMOs), including nanosized ferric oxides, manganese oxides, aluminum oxides, titanium oxides, magnesium oxides and cerium oxides, provide high surface area and specific affinity for heavy metal adsorption from aqueous systems. To date, it has become a hot topic to develop new technologies to synthesize NMOs, to evaluate their removal of heavy metals under varying experimental conditions, to reveal the underlying mechanism responsible for metal removal based on modern analytical techniques (XAS, ATR-FT-IR, NMR, etc.) or mathematical models, and to develop metal oxide-based materials of better applicability for practical use (such as granular oxides or composite materials). The present review mainly focuses on NMOs' preparation, their physicochemical properties, adsorption characteristics and mechanism, as well as their application in heavy metal removal. In addition, porous host supported NMOs are particularly concerned because of their great advantages for practical application as compared to the original NMOs. Also, some magnetic NMOs were included due to their unique separation performance. (c) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:317 / 331
页数:15
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