Measurements of H2 solubility in saline solutions under reservoir conditions: preliminary results from project H2STORE

被引：38

作者：

De Lucia, Marco ^{[1
]}

Pilz, Peter ^{[2
]}

Liebscher, Axel ^{[2
]}

Kuhn, Michael ^{[1
]}

机构：

[1] GFZ German Res Ctr Geosci, Sect Hydrogeol 5 3, D-14473 Potsdam, Germany

[2] GFZ German Res Ctr Geosci, CGS, D-14473 Potsdam, Germany

来源：

EUROPEAN GEOSCIENCES UNION GENERAL ASSEMBLY 2015 - DIVISION ENERGY, RESOURCES AND ENVIRONMENT, EGU 2015 | 2015年 / 76卷

关键词：

Hydrogen Storage; Solubility; Fluid-fluid interactions; PRESSURES; HYDROGEN; TEMPERATURES; WATER;

D O I：

10.1016/j.egypro.2015.07.892

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

A high-pressure/high-temperature reactor has been used to lead PVT and ii,solubility experiments in saline solutions covering conditions for which no data are available in literature: salinity up to halite concentration, pressure up to 200 bar and temperature up to 373 K. The hereby presented preliminary results show significant deviations from theoretical models. Further analysis and more measurements are needed to assess precision and reproducibility of these measurements; however they pinpoint the importance of experimental work to reliably constrain predictive models. (C) 2015 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecomons.org/licenses/by-nc-nd/4.0/).

引用

页码：487 / 494

页数：8

共 6 条

[1] THE SOLUBILITY OF HYDROGEN IN WATER AND IN 2-AMINOETHANOL AT TEMPERATURES BETWEEN 323-K AND 423-K AND PRESSURES UP TO 16-MPA [J].

KLING, G ;

MAUER, G .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1991, 23 (06) :531-541

[2]

Parkhurst D., 1999, USERS GUIDE PHREEQC

[3] PRESSURE-VOLUME-TEMPERATURE-CONCENTRATION RELATION OF AQUEOUS NACL SOLUTIONS [J].

ROWE, AM ;

CHOU, JCS .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1970, 15 (01) :61-&

[4] Burnett PVT Measurements of Hydrogen and the Development of a Virial Equation of State at Pressures up to 100 MPa [J].

Sakoda, N. ;

Shindo, K. ;

Motomura, K. ;

Shinzato, K. ;

Kohno, M. ;

Takata, Y. ;

Fujii, M. .

INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2012, 33 (03) :381-395

[5] FUGACITY COEFFICIENTS OF H-2, CO2, CH4, H2O AND OF H2O-CO2-CH4 MIXTURES - A VIRIAL EQUATION TREATMENT FOR MODERATE PRESSURES AND TEMPERATURES APPLICABLE TO CALCULATIONS OF HYDROTHERMAL BOILING [J].

SPYCHER, NF ;

REED, MH .

GEOCHIMICA ET COSMOCHIMICA ACTA, 1988, 52 (03) :739-749

[6] EQUILIBRIUM SOLUBILITIES OF METHANE, CARBON-MONOXIDE, AND HYDROGEN IN WATER AND SEA-WATER [J].

WIESENBURG, DA ;

GUINASSO, NL .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1979, 24 (04) :356-360

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