Photoelectrocatalytic degradation of organic contaminants at Bi2O3/TiO2 nanotube array electrode

被引:68
作者
Zhao, Xu [1 ]
Liu, Huijuan [1 ]
Qu, Jiuhui [1 ]
机构
[1] Chinese Acad Sci, State Key Lab Environm Aquat Chem, Res Ctr Ecoenvironm Sci, Beijing 100085, Peoples R China
基金
中国国家自然科学基金;
关键词
TiO2 nanotube array; Bi2O3; Photoelectrocatalysis; Visible light; Photocatalyst; PHOTOCATALYTIC ACTIVITY;
D O I
10.1016/j.apsusc.2010.12.099
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the current work, TiO2 nanotube array was prepared via electrochemical anode method. Then the Bi2O3 nanoparticles were deposited onto the TiO2 nanotube array via dip-coating method from an amorphous complex precursor. The crystal structures were characterized via X-ray diffraction analysis. Their surface textures were observed via electron-scanning microscope. The prepared composite array electrode exhibited high photoelectrocatalytic activities towards degrading organic contaminants under visible light irradiation. High photoelectrocatalytic activities were also exhibited under UV light irradiation. The catalytic mechanism was discussed based on the analysis of electrochemical and degradation kinetics results. It is suggested a P (Bi2O3)-N (TiO2) junction was formed to increase the catalytic activates. The stability of the electrode materials was confirmed finally. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:4621 / 4624
页数:4
相关论文
共 12 条
[1]   Visible-light responsive C,N-codoped Titania hollow spheres for X-3B dye photodegradation [J].
Ao, Yanhui ;
Xu, Jingjing ;
Fu, Degang ;
Yuan, Chunwei .
MICROPOROUS AND MESOPOROUS MATERIALS, 2009, 118 (1-3) :382-386
[2]   Photocatalytic activity of CU2O/TiO2, Bi2O3/TiO2 and ZnMn2O4/TiO2 heterojunctions [J].
Bessekhouad, Y ;
Robert, D ;
Weber, JV .
CATALYSIS TODAY, 2005, 101 (3-4) :315-321
[3]   Heterojunctioned BiOCl/Bi2O3, a new visible light photocatalyst [J].
Chai, Seung Yong ;
Kim, Yong Joo ;
Jung, Myong Hak ;
Chakraborty, Ashok Kumar ;
Jung, Dongwoon ;
Lee, Wan In .
JOURNAL OF CATALYSIS, 2009, 262 (01) :144-149
[4]   Preparation of a novel TiO2-based p-n junction nanotube photocatalyst [J].
Chen, YS ;
Crittenden, JC ;
Hackney, S ;
Sutter, L ;
Hand, DW .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (05) :1201-1208
[5]   Spray pyrolysed bismuth oxide thin films and their characterization [J].
Gujar, T. P. ;
Shinde, V. R. ;
Lokhande, C. D. .
MATERIALS RESEARCH BULLETIN, 2006, 41 (08) :1558-1564
[6]   Surface phases and photocatalytic activity correlation of Bi2O3/Bi2O4-x nanocomposite [J].
Hameed, Abdul ;
Montini, Tiziano ;
Gombac, Valentina ;
Fornasiero, Paolo .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (30) :9658-+
[7]   Photocatalytic activity of zinc modified Bi2O3 [J].
Hameed, Abdul ;
Gombac, Valentina ;
Montini, Tiziano ;
Felisari, Laura ;
Fornasiero, Paolo .
CHEMICAL PHYSICS LETTERS, 2009, 483 (4-6) :254-261
[8]   Synthesis, characterization and photocatalytic activity of NiO-Bi2O3 nanocomposites [J].
Hameed, Abdul ;
Gombac, Valentina ;
Montini, Tiziano ;
Graziani, Mauro ;
Fornasiero, Paolo .
CHEMICAL PHYSICS LETTERS, 2009, 472 (4-6) :212-216
[9]   Photoeletrocatalytic Activity of a Cu2O-Loaded Self-Organized Highly Oriented TiO2 Nanotube Array Electrode for 4-Chlorophenol Degradation [J].
Hou, Yang ;
Li, Xinyong ;
Zou, Xuejun ;
Quan, Xie ;
Chen, Guchua .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2009, 43 (03) :858-863
[10]   TiO2 Nanotubes with Tunable Morphology, Diameter, and Length: Synthesis and Photo-Electrical/Catalytic Performance [J].
Wang, Daoai ;
Liu, Ying ;
Yu, Bo ;
Zhou, Feng ;
Liu, Weimin .
CHEMISTRY OF MATERIALS, 2009, 21 (07) :1198-1206