Redetermination of bis(2,4-pentanedionato)-palladium(II)

被引：26

作者：

Hamid, M

Zeller, M

Hunter, AD

Mazhar, M ^{[1
]}

Tahir, AA

机构：

[1] Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan

[2] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷

关键词：

D O I：

10.1107/S1600536805030692

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of the title compound, [Pd(C5H7O2)(2)], has been redetermined at 100 K using modern equipment, resulting in improved precision compared to the previous study [Knyazeva et al. (1970). Zh. Strukt. Khim. 11, 938-939]. The new measurements reveal that the plane of the 2,4-pentanedionate ligand is tilted by 3.4 (1)degrees with respect to the PdO4 unit (Pd site symmetry = 1). Possible reasons for this bending are examined in terms of previously undiscussed intermolecular interactions.

引用

页码：M2181 / M2183

页数：3

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