P3HT:PCBM and Cu2SnSe3 nano-ink based hybrid solar cells

被引：8

作者：

Dwivedi, Shailendra Kumar ^{[1
,2
]}

Tiwari, D. C. ^{[1
,2
]}

Tripathi, Santosh K. ^{[3
]}

Zaman, M. Burhanuz ^{[2
]}

Dipak, Pukhrambam ^{[2
]}

Imamuddin, Mohd. ^{[3
]}

Poolla, Rajaram ^{[2
]}

Prasad, N. Eswara ^{[3
]}

机构：

[1] Jiwaji Univ, Sch Studies Elect, Gwalior, MP, India

[2] Jiwaji Univ, Sch Studies Phys, Gwalior, MP, India

[3] Def Mat & Stores Res & Dev Estab, Kanpur, UP, India

来源：

SOLAR ENERGY | 2019年 / 177卷

关键词：

Nano-ink; P3HT:PCBM; Hybrid solar cell;

D O I：

10.1016/j.solener.2018.11.032

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

In this work, we report the synthesis of Copper Tin Selenide (Cu2SnSe3) nanocrystals by solvothermal method. We have fabricated for the first time, the heterojunction hybrid solar cells using blend of poly(3-hexyle thiophene) (P3HT):[6, 6]phenyl-C61-butyric-acid-methyl-ester (PCBM) and Cu2SnSe3 (CTSe) nano-ink as an additional photoactive layer. Electrochemical impedance spectroscopy (EIS) of fabricated devices are carried out under dark condition on applied bias of 0.1 V with frequency ranging from 1 Hz to 1 MHz. It was found that the charge storage capacity of the device based on CTSe nano-ink/P3HT:PCBM as an photo absorber, was greater than the device without P3HT:PCBM layer. We have obtained open circuit voltage (V-oc) of 565 mV, current density (J(sc)) of 0.87 mA/cm(2) and fill factor (FF) of 0.48 from the hybrid solar cells. This method is novel and cost effective for preparing stable nano-ink, which can be used in printable optoelectronics devices for large area production.

引用

页码：382 / 386

页数：5

共 25 条

[1] Synthesis of Cu2SnSe3 Nanocrystals for Solution Processable Photovoltaic Cells [J].

Ahmadi, Mahshid ;

Pramana, Stevin S. ;

Batabyal, Sudip K. ;

Boothroyd, Chris ;

Mhaisalkar, Subodh G. ;

Lam, Yeng Ming .

INORGANIC CHEMISTRY, 2013, 52 (04) :1722-1728

[2] A High Efficiency Electrodeposited Cu2ZnSnS4 Solar Cell [J].

Ahmed, Shafaat ;

Reuter, Kathleen B. ;

Gunawan, Oki ;

Guo, Lian ;

Romankiw, Lubomyr T. ;

Deligianni, Hariklia .

ADVANCED ENERGY MATERIALS, 2012, 2 (02) :253-259

[3] Device characteristics of a 10.1% hydrazine-processed Cu2ZnSn(Se,S)4 solar cell [J].

Barkhouse, D. Aaron R. ;

Gunawan, Oki ;

Gokmen, Tayfun ;

Todorov, Teodor K. ;

Mitzi, David B. .

PROGRESS IN PHOTOVOLTAICS, 2012, 20 (01) :6-11

[4] Investigations on co-evaporated Cu2SnSe3 and Cu2SnSe3-ZnSe thin films [J].

Bhaskar, P. Uday ;

Babu, G. Suresh ;

Kumar, Y. B. Kishore ;

Raja, V. Sundara .

APPLIED SURFACE SCIENCE, 2011, 257 (20) :8529-8534

[5] Ultrasonically assisted sol-gel synthesis of nanocrystalline Cu2ZnSnS4 particles for solar cell applications [J].

Chandel, Tarun ;

Thakur, Vikas ;

Zaman, M. Burhanuz ;

Dwivedi, Shailendra Kumar ;

Poolla, Rajaram .

MATERIALS LETTERS, 2018, 212 :279-282

[6] Bulk-heterojunction hybrid solar cells with non-toxic, earth abundant stannite phase CuZn2AlS4 nanocrystals [J].

Chaudhary, Dhirendra K. ;

Ghosh, Anima ;

Thangavel, R. ;

Kumar, Lokendra .

THIN SOLID FILMS, 2018, 649 :202-209

[7]

Chen R., 2016, SCI REP-UK, V6, P3

[8]

Ding Y., 2008, P SOC PHOTO-OPT INS, V7099

[9] Absorption and crystallinity of poly(3-hexylthiophene)/fullerene blends in dependence on annealing temperature [J].

Erb, T ;

Zhokhavets, U ;

Hoppe, H ;

Gobsch, G ;

Al-Ibrahim, M ;

Ambacher, O .

THIN SOLID FILMS, 2006, 511 :483-485

[10] Efficient hybrid solar cell with P3HT:PCBM and Cu2ZnSnS4 nanocrystals [J].

Jang, Se-Jeong ;

Nhu Thuy Ho ;

Kim, Yong Soo .

33RD INTERNATIONAL CONFERENCE ON THE PHYSICS OF SEMICONDUCTORS, 2017, 864

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