Size- and Temperature-Dependent Charge Transport in PbSe Nanocrystal Thin Films

We report the size- and temperature-dependence of electron transport in thin films of PbSe nanocrystals. Upon increasing temperature over the range 28-200 K, the electron transport underwent a transition in mechanism from Efros-Shklovskii-variable-range-hopping (ES-VRH) to nearest-neighbor-hopping (NNH). The transition occurred at higher temperatures for films with smaller particles. The electron localization length, estimated from the ES-VRH model, was comparable to the nanocrystal size and scaled systematically with nanocrystal diameter. The activation energy from the NNH regime was also size-dependent, which is attributed both to size-dependent Coulomb effects and the size-distribution of nanocrystals.