Calix[4]pyrrole-Based Azo-Bridged Porous Organic Polymer for Bromine Capture

被引：60

作者：

Chen, Di ^{[1
]}

Luo, Dan ^{[1
]}

He, Yanlei ^{[1
]}

Tian, Jinya ^{[1
]}

Yu, Yao ^{[1
]}

Wang, Hongyu ^{[2
,3
]}

Sessler, Jonathan L. ^{[4
]}

Chi, Xiaodong ^{[1
]}

机构：

[1] Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mold Technol, Wuhan 430074, Peoples R China

[2] Shanghai Univ, Coll Sci, Dept Chem, Shanghai 200444, Peoples R China

[3] Shanghai Univ, Ctr Supramol Chem & Catalysis, Shanghai 200444, Peoples R China

[4] Univ Texas Austin, Dept Chem, Austin, TX 78712 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2022年 / 144卷 / 37期

基金：

中国国家自然科学基金;

关键词：

IODINE CAPTURE; FRAMEWORKS; RECOGNITION; REMOVAL; MICROPOLLUTANTS; NETWORK;

D O I：

10.1021/jacs.2c08327

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The toxicity, corrosiveness, and volatility of elemental bromine presents challenges for its safe storage and transportation. Purification from other halogens is also difficult. Here, we report an easy-to-prepare calix[4]pyrrole-based azobridged porous organic polymer (C4P-POP) that supports efficient bromine capture. C4P-POP was found to capture bromine as a vapor and from a cyclohexane source phase with maximum uptake capacities of 3.6 and 3.4 g.g(-1), respectively. Flow-through adsorption experiments revealed that C4P-POP removes 80% of the bromine from a 4.0 mM cyclohexane solution at a flow rate of 45 mL.h(-1). C4P-POP also allowed the selective capture of bromine from a 1:1 mixture of bromine and iodine in cyclohexane.

引用

页码：16755 / 16760

页数：6

共 53 条

[1] Post-Synthetically Elaborated BODIPY-Based Porous Organic Polymers (POPs) for the Photochemical Detoxification of a Sulfur Mustard Simulant [J].

Atilgan, Ahmet ;

Cetin, M. Mustafa ;

Yu, Jierui ;

Beldjoudi, Yassine ;

Liu, Jian ;

Stern, Charlotte L. ;

Cetin, Furkan M. ;

Islamoglu, Timur ;

Farha, Omar K. ;

Deria, Pravas ;

Stoddart, J. Fraser ;

Hupp, Joseph T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (43) :18554-18564

[2] A calix[4]pyrrole-based linear supramolecular polymer constructed by orthogonal self-assembly [J].

Budak, Aysegul ;

Aydogan, Abdullah .

CHEMICAL COMMUNICATIONS, 2021, 57 (34) :4186-4189

[3] Macrocycle-derived hierarchical porous organic polymers: synthesis and applications [J].

Chen, Weiben ;

Chen, Pei ;

Zhang, Guang ;

Xing, Guolong ;

Feng, Yu ;

Yang, Ying-Wei ;

Chen, Long .

CHEMICAL SOCIETY REVIEWS, 2021, 50 (20) :11684-11714

[4] Molecular Recognition Under Interfacial Conditions: Calix[4]pyrrole-Based Cross-linkable Micelles for Ion Pair Extraction [J].

Chi, Xiaodong ;

Peters, Gretchen Marie ;

Hammel, Forrest ;

Brockman, Chandler ;

Sessler, Jonathan L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (27) :9124-9127

[5] Tetra-phosphonate Calix[4]pyrrole Cavitands as Multitopic Receptors for the Recognition of Ion Pairs [J].

Ciardi, Moira ;

Galan, Albano ;

Ballester, Pablo .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (05) :2047-2055

[6] Calix[4]pyrrole: An old yet new ion-pair receptor [J].

Custelcean, R ;

Delmau, LH ;

Moyer, BA ;

Sessler, JL ;

Cho, WS ;

Gross, D ;

Bates, GW ;

Brooks, SJ ;

Light, ME ;

Gale, PA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (17) :2537-2542

[7] Macrocyclic Arenes-Based Conjugated Macrocycle Polymers for Highly Selective CO2 Capture and Iodine Adsorption [J].

Dai, Dihua ;

Yang, Jie ;

Zou, Yong-Cun ;

Wu, Jia-Rui ;

Tan, Li-Li ;

Wang, Yan ;

Li, Bao ;

Lu, Tong ;

Wang, Bo ;

Yang, Ying-Wei .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (16) :8967-8975

[8] Advances in anion transport and supramolecular medicinal chemistry [J].

Davis, Jeffery T. ;

Gale, Philip A. ;

Quesada, Roberto .

CHEMICAL SOCIETY REVIEWS, 2020, 49 (16) :6056-6086

[9] Ionic Covalent Organic Frameworks with Spiroborate Linkage [J].

Du, Ya ;

Yang, Haishen ;

Whiteley, Justin Michael ;

Wan, Shun ;

Jin, Yinghua ;

Lee, Se-Hee ;

Zhang, Wei .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (05) :1737-1741

[10] A novel calix[4]pyrrole derivative as a potential anticancer agent that forms genotoxic adducts with DNA [J].

Geretto, Marta ;

Ponassi, Marco ;

Casale, Martina ;

Pulliero, Alessandra ;

Cafeo, Grazia ;

Malagreca, Ferdinando ;

Profumo, Aldo ;

Balza, Enrica ;

Bersimbaev, Rakhmetkazhi ;

Kohnke, Franz Heinrich ;

Rosano, Camillo ;

Izzotti, Alberto .

SCIENTIFIC REPORTS, 2018, 8

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