Determination of the Lewis acidity of ionic liquids by means of an IR spectroscopic probe

被引:250
作者
Yang, YL [1 ]
Kou, Y [1 ]
机构
[1] Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
关键词
D O I
10.1039/b311615h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pyridine and ethanenitrile can be used as molecular probes to measure the Lewis acidities of ionic liquids by monitoring the shift of IR absorption bands near 1450 cm(-1) for pyridine and in the range 2250-2340 cm(-1) for ethanenitrile.
引用
收藏
页码:226 / 227
页数:2
相关论文
共 22 条
[1]   OPTICAL VS THERMODYNAMIC BASICITIES - PROBE PB2+ ION SPECTRA IN THERMODYNAMICALLY CHARACTERIZED MOLTEN CHLOROALUMINATE SOLUTIONS [J].
ANGELL, CA ;
BENNETT, PD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (23) :6304-6309
[2]   COMPLEXATION OF CP2MCL2 IN A CHLOROALUMINATE MOLTEN-SALT - RELEVANCE TO HOMOGENEOUS ZIEGLER-NATTA CATALYSIS [J].
CARLIN, RT ;
WILKES, JS .
JOURNAL OF MOLECULAR CATALYSIS, 1990, 63 (02) :125-129
[3]   DETERMINATION OF ALUMINUM ELECTRONEGATIVITY IN NEW AMBIENT-TEMPERATURE ACIDIC MOLTEN-SALTS BASED ON 3-BUTYL-1-METHYLIMIDAZOLIUM CHLORIDE AND ALET3-XCLX (X = 0-3) BY H-1 NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY [J].
CHAUVIN, Y ;
DIMARCOVANTIGGELEN, F ;
OLIVIER, H .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (07) :1009-1011
[4]   Novel bronsted acidic ionic liquids and their use as dual solvent-catalysts [J].
Cole, AC ;
Jensen, JL ;
Ntai, I ;
Tran, KLT ;
Weaver, KJ ;
Forbes, DC ;
Davis, JH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (21) :5962-5963
[5]   From curiosities to commodities: ionic liquids begin the transition [J].
Davis, JH ;
Fox, PA .
CHEMICAL COMMUNICATIONS, 2003, (11) :1209-1212
[6]   PROPERTIES OF 1,3-DIALKYLIMIDAZOLIUM CHLORIDE ALUMINUM-CHLORIDE IONIC LIQUIDS .1. ION INTERACTIONS BY NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY [J].
FANNIN, AA ;
KING, LA ;
LEVISKY, JA ;
WILKES, JS .
JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (12) :2609-2614
[7]   New developments in catalysis using ionic liquids [J].
Gordon, CM .
APPLIED CATALYSIS A-GENERAL, 2001, 222 (1-2) :101-117
[8]   AL-27 NUCLEAR MAGNETIC-RESONANCE STUDY OF THE ROOM-TEMPERATURE MELT ALCL3-NORMAL-BUTYLPYRIDINIUM CHLORIDE [J].
GRAY, JL ;
MACIEL, GE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (24) :7147-7151
[9]   Lewis acidity dependency of the electrochemical window of zinc chloride-1-ethyl-3-methylimidazolium chloride ionic liquids [J].
Hsiu, SI ;
Huang, JF ;
Sun, IW ;
Yuan, CH ;
Shiea, J .
ELECTROCHIMICA ACTA, 2002, 47 (27) :4367-4372