Cu(I)-catalyzed cycloguanidination of olefins

被引：63

作者：

Zhao, Baoguo ^{[1
]}

Du, Haifeng ^{[1
]}

Shi, Yian ^{[1
]}

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 06期

关键词：

D O I：

10.1021/ol702974s

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This paper describes a novel cycloguanidination process using CuCl as catalyst and diaziridinimines as the nitrogen source. A variety of conjugated dienes, trienes, and terminal olefins can be effectively diaminated under mild reaction conditions, For dienes and trienes, the reaction occurs at the terminal double bond with high regioselectivity.

引用

页码：1087 / 1090

页数：4

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