Synthesis, Structure, and Reactivity of Carbene-Stabilized Phosphorus(III)-Centered Trications [L3P]3+

被引：65

作者：

Petuskova, Jekaterina ^{[1
]}

Patil, Mahendra ^{[1
]}

Holle, Sigrid ^{[1
]}

Lehmann, Christian W. ^{[1
]}

Thiel, Walter ^{[1
]}

Alcarazo, Manuel ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 51期

关键词：

METAL; LIGANDS; PHOSPHINE; COMPLEXES; BEHAVIOR;

D O I：

10.1021/ja210223s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbene-stabilized [L3P](+3) cations have been synthesized for the first time by a reaction between 1-chloro-2,3-bis(dialkylamino)cyclopropenium salts and P(SiMe3)(3). In addition, the first structural characterization of such an entity is reported. Consistent with the X-ray data, density functional calculations indicate that these P-centered cations, despite their high positive charge, still feature a nonbonding electron pair on the P-atom (HOMO) and a very low-lying LUMO depicting them as poor sigma-donors and excellent pi-acceptors.

引用

页码：20758 / 20760

页数：3

共 39 条

[1] Imidazoliophosphines are True N-Heterocyclic Carbene (NHC)-Phosphenium Adducts [J].

Abdellah, Ibrahim ;

Lepetit, Christine ;

Canac, Yves ;

Duhayon, Carine ;

Chauvin, Remi .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (44) :13095-13108

[2] N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands [J].

Asay, Matthew ;

Jones, Cameron ;

Driess, Matthias .

CHEMICAL REVIEWS, 2011, 111 (02) :354-396

[3] Synthesis of New Cationic Donor-Stabilized Phosphenium Adducts and Their Unexpected P-Substituent Exchange Reactions [J].

Azouri, Michele ;

Andrieu, Jacques ;

Picquet, Michel ;

Cattey, Helene .

INORGANIC CHEMISTRY, 2009, 48 (03) :1236-1242

[4]

Bart J. C. J., 1969, J CHEM SOC B, V28, P763

[5] SYNTHESIS OF ONIO-SUBSTITUTED, DIONIO-SUBSTITUTED, AND TRIONIO-SUBSTITUTED PHOSPHINES - THE NUCLEOPHILIC BEHAVIOR OF DBN AND DBU TOWARD MAIN-GROUP ELECTROPHILES [J].

BOUHADIR, G ;

REED, RW ;

REAU, R ;

BERTRAND, G .

HETEROATOM CHEMISTRY, 1995, 6 (04) :371-375

[6] Synthesis and Coordination Properties of Nitrogen(I)-Based Ligands [J].

Bruns, Hans ;

Patil, Mahendra ;

Carreras, Javier ;

Vazquez, Arcadio ;

Thiel, Walter ;

Goddard, Richard ;

Alcarazo, Manuel .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (21) :3680-3683

[7] New synthetic opportunities using Lewis acidic phosphines [J].

Burford, N ;

Ragogna, PJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (23) :4307-4315

[8] Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry [J].

Clavier, Herve ;

Nolan, Steven P. .

CHEMICAL COMMUNICATIONS, 2010, 46 (06) :841-861

[9] A Lewis-basic, dionio-substituted phosphane [J].

Coles, Martyn P. ;

Hitchcock, Peter B. .

CHEMICAL COMMUNICATIONS, 2007, (48) :5229-5231

[10] The Measure of All Rings-N-Heterocyclic Carbenes [J].

Droege, Thomas ;

Glorius, Frank .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (39) :6940-6952

← 1 2 3 4 →