Emission of gases and degradation volatiles from polymeric wood constituents in friction welding of wood dowels

Analysis of volatile compounds and gases emitted as smoke at the welding interface during rotational wood dowel welding of a hardwood (beech) and of a softwood (Norway spruce) has shown that the compounds in such a smoke are water vapour, CO2, degradation compounds from wood polymeric carbohydrates and from amorphous lignin, as well as some volatile terpenes, these latter only for the softwood used, Norway spruce. The main carbohydrates contributing to the volatile compounds are xylans for beech and glucomannans for spruce. Numerous compounds, in very small proportions derived from the degradation and rearrangement reactions of lignin, have also been identified. The proportion Of CO2 emitted is very low, and neither CO nor methane is emitted due to the relatively low temperature of dowel welding. Experiments at temperature slightly higher than that of dowel welding but prolonged in time have shown that the main component of the smoke produced during welding appears to be water vapour. (c) 2008 Elsevier Ltd. All rights reserved.