The Role of Alkyl Chain Length and Halide Counter Ion in Layered Dion-Jacobson Perovskites with Aromatic Spacers

被引:30
作者
Ducinskas, Algirdas [1 ,2 ]
Fish, George C. [3 ]
Hope, Michael A. [4 ]
Merten, Lena [5 ]
Moia, Davide [2 ]
Hinderhofer, Alexander [5 ]
Carbone, Loie C. [1 ]
Moser, Jacques-Edouard [3 ]
Schreiber, Frank [5 ]
Maier, Joachim [2 ]
Milic, Jovana, V [1 ,6 ]
Graetzel, Michael [1 ]
机构
[1] Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland
[2] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany
[3] Ecole Polytech Fed Lausanne, Photochem Dynam Grp, CH-1015 Lausanne, Switzerland
[4] Ecole Polytech Fed Lausanne, Lab Magnet Resonance, CH-1015 Lausanne, Switzerland
[5] Univ Tubingen, Inst Angew Phys, D-72076 Tubingen, Germany
[6] Univ Fribourg, Adolphe Merkle Inst, CH-1700 Fribourg, Switzerland
基金
瑞士国家科学基金会;
关键词
HYBRID PEROVSKITES; IODIDE PEROVSKITES; OPTICAL-PROPERTIES; LEAD; ABSORPTION; EFFICIENT; ENABLES;
D O I
10.1021/acs.jpclett.1c02937
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Layered hybrid perovskites based on Dion Jacobson phases are of interest to various optoelectronic applications. However, the understanding of their structure-property relationships remains limited. Here, we present a systematic study of Dion Jacobson perovskites based on (S)PbX4 (n = 1) compositions incorporating phenylene-derived aromatic spacers (s) with different anchoring alkylammonium groups and halides (X = I, Br). We focus our study on 1,4-phenylenediammonium (PDA), 1,4-phenylenedimethylammonium (PDMA), and 1,4-phenylenediethylammonium (PDEA) spacers. Systems based on PDA did not form a well-defined layered structure, showing the formation of a 1D structure instead, whereas the extension of the alkyl chains to PDMA and PDEA rendered them compatible with the formation of a layered structure, as shown by X-ray diffraction and solid-state NMR spectroscopy. In addition, the control of the spacer length affects optical properties and environmental stability, which is enhanced for longer alkyl chains and bromide compositions. This provides insights into their design for optoelectronic applications.
引用
收藏
页码:10325 / 10332
页数:8
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