Platinum group metal-free Fe-based (Fe-N-C) oxygen reduction electrocatalysts for direct alcohol fuel cells

被引：26

作者：

Berretti, Enrico ^{[1
]}

Longhi, Mariangela ^{[2
]}

Atanassov, Plamen ^{[3
]}

Sebastian, David ^{[4
]}

Lo Vecchio, Carmelo ^{[5
]}

Baglio, Vincenzo ^{[5
]}

Serov, Alexey ^{[6
]}

Marchionni, Andrea ^{[1
]}

Vizza, Francesco ^{[1
]}

Santoro, Carlo ^{[7
]}

Lavacchi, Alessandro ^{[1
]}

机构：

[1] CNR, Ist Chim Composti Organomet ICCOM, Via Madonna Piano 10, I-50019 Florence, Italy

[2] Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy

[3] Univ Calif Irvine, Natl Fuel Cells Res Ctr, Dept Chem & Biomol Engn, Irvine, CA 92697 USA

[4] CSIC, Inst Carboquim, C Miguel Luesma Castan 4, Zaragoza 50018, Spain

[5] CNR, ITAE, Ist Tecnol Avanzate Energia Nicola Giordano, Via Salita S Lucia 5, I-98126 Messina, Italy

[6] Pajarito Powder LLC, 3600 Osuna Rd NE,Ste 309, Albuquerque, NM 87109 USA

[7] Univ Milano Bicocca, Dept Mat Sci, U5 Via Cozzi 55, I-20125 Milan, Italy

来源：

CURRENT OPINION IN ELECTROCHEMISTRY | 2021年 / 29卷

关键词：

Direct alcohol fuel cell; Platinum group metal-free catalysts; Cathode; Alcohol tolerance; HIGH-PERFORMANCE; METHANOL CROSSOVER; CATHODE CATALYSTS; IRON; TOLERANCE;

D O I：

10.1016/j.coelec.2021.100756

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In direct alcohol fuel cells (DAFCs), the oxidation of alcohols happens at the expenses of the oxygen reduction reaction at the cathode. DAFCs' cathodes use a significant amount of platinum that is an expensive critical raw material. Moreover, platinum oxidizes alcohols, a fact that combined with alcohol crossover, decreases significantly the performance of the cells. The use of Fe-based (Fe-N-C) platinum group metal-free (PGM-free) cathodes is a convenient strategy to overcome these limitations. This review analyzes the application of PGM-free cathodes to DAFCs. The discussion focuses on acidic systems and covers the following subjects: (i) the breakdown of DAFC potential in its components, (ii) the analysis of the advantages from the use of the PGM-free cathode, and (iii) a review of the performance and durability of DAFCs. The review closes with a view of the authors of the future perspective for the research.

引用

页数：11

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