Optical properties of ZnS-CdS alloy quantum dots prepared by a colloidal method

被引:22
作者
Tomihira, K [1 ]
Kim, D [1 ]
Nakayama, M [1 ]
机构
[1] Osaka City Univ, Grad Sch Engn, Dept Appl Phys, Sumiyoshi Ku, Osaka 5588585, Japan
关键词
quantum dot; colloidal method; luminescence; photoetching;
D O I
10.1016/j.jlumin.2004.09.011
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We have investigated optical properties of ZnS-CdS alloy (Zn1-xCdxS) quantum dots (QDs) prepared by a colloidal method. We succeeded in the preparation of Zn1-xCdxS QDs for all alloy compositions of x between 0 and 1. Furthermore, the reduction of the size-distribution width was achieved by using a size-selective photoetching treatment. The intensity of the band-edge luminescence was remarkably increased by modifying the surface with a Cd(OH)(2) layer. The surface modification also causes drastic changes of decay profiles of the band-edge luminescence, reflecting considerable suppression of nonradiative decay processes. These results clearly demonstrate the success in the preparation of the size- and surface-controlled Zn1-xCdxS QDs. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:131 / 135
页数:5
相关论文
共 9 条
[2]   Preparation of semiconductor nanoparticle-polymer composites by direct reverse micelle polymerization using polymerizable surfactants [J].
Hirai, T ;
Watanabe, T ;
Komasawa, I .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (38) :8962-8966
[3]   Surface-modification effects on luminescence properties of CdS and CdMnS quantum dots prepared by a reverse-micelle method [J].
Kim, D ;
Miyamoto, M ;
Nakayama, M .
2ND INTERNATIONAL CONFERENCE ON SEMICONDUCTOR QUANTUM DOTS, 2003, :1233-1236
[4]   Self-narrowing and photoetching effects on the size distribution of CdS quantum dots prepared by a reverse-micelle method [J].
Kim, D ;
Teratani, N ;
Nakayama, M .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2002, 41 (08) :5064-5068
[5]   Photo-irradiation effects on preparation of colloidal quantum dots and their surface modification [J].
Kim, D ;
Teratani, N ;
Mizoguchi, K ;
Nishimura, H ;
Nakayama, M .
INTERNATIONAL JOURNAL OF MODERN PHYSICS B, 2001, 15 (28-30) :3829-3832
[6]   Solid solution of Cd1-yMnyS nanocrystals [J].
Levy, L ;
Ingert, D ;
Feltin, N ;
Briois, V ;
Pileni, MP .
LANGMUIR, 2002, 18 (05) :1490-1493
[7]  
MADELUNG O, 1982, PHYS 2 6 1 7 COMPO B, V17, P474
[8]   Preparation of monodisperse CdS nanocrystals by size selective photocorrosion [J].
Matsumoto, H ;
Sakata, T ;
Mori, H ;
Yoneyama, H .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (32) :13781-13785
[9]   PHOTOCHEMISTRY OF COLLOIDAL SEMICONDUCTORS .20. SURFACE MODIFICATION AND STABILITY OF STRONG LUMINESCING CDS PARTICLES [J].
SPANHEL, L ;
HAASE, M ;
WELLER, H ;
HENGLEIN, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (19) :5649-5655